(1S,2S)-1,2-Bis(2-hydroxyphenyl)-1,2-ethanediamine

Base Information

Chemical Name:(1S,2S)-1,2-Bis(2-hydroxyphenyl)-1,2-ethanediamine
CAS No.:119386-71-9
Molecular Formula:C14H16N2O2
Molecular Weight:244.28900
Hs Code.:
Mol file:119386-71-9.mol

Synonyms:

Suppliers and Price of (1S,2S)-1,2-Bis(2-hydroxyphenyl)-1,2-ethanediamine

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Strem Chemicals
(1S,2S)-1,2-Bis(2-hydroxyphenyl)ethane-1,2-diamine, min. 97%
1g
$ 87.00

Strem Chemicals
(1S,2S)-1,2-Bis(2-hydroxyphenyl)ethane-1,2-diamine, min. 97%
250mg
$ 49.00

Sigma-Aldrich
(1S,2S)-1,2-Bis(2-hydroxyphenyl)ethylenediamine 95%
1g
$ 140.00

Sigma-Aldrich
(1S,2S)-1,2-Bis(2-hydroxyphenyl)ethylenediamine 95%
10g
$ 363.00

American Custom Chemicals Corporation
(1S,2S)-1,2-BIS(2-HYDROXYPHENYL)ETHYLENEDIAMINE 95.00%
1G
$ 297.15

Total 9 raw suppliers

Chemical Property of (1S,2S)-1,2-Bis(2-hydroxyphenyl)-1,2-ethanediamine

Chemical Property:

Melting Point:157-162?°C
Boiling Point:457.9±40.0 °C(Predicted)
PKA:9.15±0.35(Predicted)
PSA：92.50000
Density:1.294±0.06 g/cm3(Predicted)
LogP:3.19820
Sensitive.:air sensitive

Purity/Quality:

98%,99%, ^*data from raw suppliers

(1S,2S)-1,2-Bis(2-hydroxyphenyl)ethane-1,2-diamine, min. 97% ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:Xn
Statements: 22

MSDS Files:

Useful:

Uses (1S,2S)-1,2-Bis(2-hydroxyphenyl)ethylenediamine can be used:As a starting material for the synthesis of Schiff base complexes of gold(III), bearing potent anticancer activity.As a stereoinductor in the synthesis of quinoline and isoquinoline based 1,2-diamines; that are employed as catalysts in the preparation of warfarin and coumachlor in water.

Technology Process of (1S,2S)-1,2-Bis(2-hydroxyphenyl)-1,2-ethanediamine

There total 14 articles about (1S,2S)-1,2-Bis(2-hydroxyphenyl)-1,2-ethanediamine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: (+/-)-1,2-bis(-2-methoxyphenyl)-1,2-ethylenediamine

: 119386-71-9,870991-68-7,870991-70-1
(SR,SR)-1,2-di-(2-hydroxyphenyl)-1,2-diaminoethane

Guidance literature:: With boron tribromide; In dichloromethane; Yield given; a) -60 deg C, 30 min, b) 3 d, RT;
DOI:10.1016/0223-5234(93)90003-W

Reference yield:

: 58519-82-7
meso-N,N'-bis(2-hydroxybenzyliden)1,2-bis(2-methoxyphenyl)ethylenediamine

: 51208-45-8,119386-71-9,870991-68-7,870991-70-1
meso-1,2-Bis-(2-hydroxyphenyl)ethylenediamine

Guidance literature:: Multi-step reaction with 2 steps

1: 93 percent / 6 N aq. H₂SO₄

2: BBr₃ / CH₂Cl₂ / a) -60 deg C, 30 min, b) 3 d, RT

With sulfuric acid; boron tribromide; In dichloromethane;
DOI:10.1016/0223-5234(93)90003-W

Reference yield:

: 58519-82-7
meso-N,N'-bis(2-hydroxybenzyliden)1,2-bis(2-methoxyphenyl)ethylenediamine

: 119386-71-9,870991-68-7,870991-70-1
(SR,SR)-1,2-di-(2-hydroxyphenyl)-1,2-diaminoethane

Guidance literature:: Multi-step reaction with 5 steps

1: 93 percent / 6 N aq. H₂SO₄

2: 81 percent / acetonitrile / 3 h

3: 49 percent / 0.17 h / Heating

4: 90 percent / 6 N aq. H₂SO₄

5: BBr₃ / CH₂Cl₂ / a) -60 deg C, 30 min, b) 3 d, RT

With sulfuric acid; boron tribromide; In dichloromethane; acetonitrile;
DOI:10.1016/0223-5234(93)90003-W