Technology Process of [PdBr2(Ph2PCH2C(Ph)=N(2,6-Me2C6H3))]
There total 1 articles about [PdBr2(Ph2PCH2C(Ph)=N(2,6-Me2C6H3))] which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
In
tetrahydrofuran;
ligand in THF was added dropwise to suspn. PdBr2 in THF and stirred at room temp. for 48 h; ppt. was filtered, washed with pentane and dried in vac.; elem. anal.;
DOI:10.1039/b102476k
- Guidance literature:
-
With
KH;
In
tetrahydrofuran;
to mixt. (PdBr2(Ph2PCH2C(Ph)=N(2,6-Me2C6H3)) and KH THF was added at -78°C and left to reach room temp. ovr 12 h, volatiles were removed under reduced pressure, residue ws washed with pentane and extd. into CH2Cl2; soln. was filtered and evapd.;
DOI:10.1039/b102476k
- Guidance literature:
-
With
KH;
In
tetrahydrofuran;
(N2); treating palladium compd. with KH in THF at -78°C;
DOI:10.1016/j.ica.2005.12.040
![[Ph<sub>2</sub>PCH<sub>2</sub>C(Ph)=N(2,6-Me<sub>2</sub>C<sub>6</sub>H<sub>3</sub>)]](/Databaselist/images/loading.webp)
