P(Me)(Ph)(p-methoxybenzyl)(BH₃)

Base Information

Chemical Name:P(Me)(Ph)(p-methoxybenzyl)(BH₃)
CAS No.:882535-72-0
Molecular Formula:C₁₅H₂₀BOP
Molecular Weight:258.108
Hs Code.:

P(Me)(Ph)(p-methoxybenzyl)(BH<sub>3</sub>)

Synonyms:

Suppliers and Price of P(Me)(Ph)(p-methoxybenzyl)(BH₃)

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of P(Me)(Ph)(p-methoxybenzyl)(BH₃)

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of P(Me)(Ph)(p-methoxybenzyl)(BH₃)

There total 2 articles about P(Me)(Ph)(p-methoxybenzyl)(BH₃) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.0%

: 14044-65-6
borane-THF

: 824-94-2
p-methoxybenzyl chloride

: 6372-48-1
methylphenylphosphine

: 882535-72-0,622837-95-0,1148015-50-2
P(Me)(Ph)(p-methoxybenzyl)(BH₃)

Guidance literature:: With NaOCH(CH₃)2CH₂CH₂; [RuH(1,2-bis(dimethylphosphino)ethane)((R)-MeO-BiPHEP)][tetraphenylborate]; In tetrahydrofuran; (N2); addn. of phosphine deriv. and benzyl chloride to THF soln. of sodium alcoholate deriv. and ruthenium compd., stirring at room temp. for 2 h, addn. of THF soln. of borane deriv., stirring at room temp. for 30 min; addn. of water, extn. (ethyl acetate), washing with brine, drying over Na2SO4, filtration, concg., chromy. (silica gel, 75:25 hexanes/ethyl acetate);

Reference yield:

: 824-94-2
p-methoxybenzyl chloride

: 501381-03-9,136172-50-4,119186-75-3
(S_p)-methylphenylphosphine borane

: 882535-72-0,622837-95-0,1148015-50-2
P(Me)(Ph)(p-methoxybenzyl)(BH₃)

Guidance literature:: With n-BuLi; In tetrahydrofuran; hexane; Schlenk techniques; soln. of (S(P))-PH(Me)(Ph)(BH3) in THF cooled to -78°C; n-BuLi in hexanes added; soln. stirred for 10 min; p-MeOC6H4 CH2Cl added; mixt. stirred -78 °C for 6 h; soln. warmed to room temp. and quenched with H2O; org. layer sepd.; aq. layer extd. with Et2O; org. exts. combined, washedwith brine, dried over MgSO4, and stripped to dryness in vacuo; gravity column chromy. (silica gel, CH2Cl2/hexanes); HPLC anal.;
DOI:10.1021/om030144x