Methylphenylphosphine

Base Information

• Chemical Name: Methylphenylphosphine
• CAS No.: 6372-48-1
• Molecular Formula: C7H9P
• Molecular Weight: 124.122
• Hs Code.: 2902909090
• European Community (EC) Number: 633-186-2
• DSSTox Substance ID: DTXSID80399505
• Nikkaji Number: J1.212.167I,J3.397.703D
• Wikidata: Q82202115
• Mol file: 6372-48-1.mol

Synonyms:METHYLPHENYLPHOSPHINE;6372-48-1;methyl(phenyl)phosphine;Methyl-phenyl-phosphane;SCHEMBL49896;SCHEMBL13265756;DTXSID80399505;MHERPFVRWOTBSF-UHFFFAOYSA-N;AKOS006282832

Chemical Property of Methylphenylphosphine

Chemical Property:

• Refractive Index: n20/D 1.57(lit.)
• Boiling Point: 59-60 °C/10 mmHg(lit.)
• PSA: 13.59000
• Density: 0.973 g/mL at 25 °C(lit.)
• LogP: 1.62020
• XLogP3: 1.5
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 1
• Exact Mass: 124.044187285
• Heavy Atom Count: 8
• Complexity: 55.4

Purity/Quality:

99% ^*data from raw suppliers

METHYLPHENYLPHOSPHINE 98.00% ^*data from reagent suppliers

Safty Information:

• Hazard Codes: F,T
• Statements: 17-23/24/25-36/37/38
• Safety Statements: 16-26-36/37/39-45

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CPC1=CC=CC=C1

Technology Process of Methylphenylphosphine

There total 21 articles about Methylphenylphosphine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 87.0%

phenylphosphane (638-21-1) + methyl iodide (74-88-4) → methylphenylphosphine (6372-48-1)

Guidance literature:

phenylphosphane; With sodium; In diethyl ether; at 35 ℃; for 1h; Inert atmosphere;

methyl iodide; In diethyl ether; at 20 - 35 ℃; for 0.5h; Inert atmosphere;

DOI:10.1002/ejoc.201001162

Reference yield: 83.0%

manganese (7439-96-5) + chloromethylphenylphosphine → methylphenylphosphine (6372-48-1)

Guidance literature:

In N,N-dimethyl-formamide; toluene;

Reference yield: 57.0%

dichloromethane (75-09-2) + phenylphosphane (638-21-1) → bis(diphenylphosphino)methane (28240-64-4) + methylphenylphosphine (6372-48-1)

Guidance literature:

With potassium hydroxide; In N,N-dimethyl-formamide; at 0 ℃; for 3h;

upstream raw materials:

methyl methylphenylphosphinate

phenylphosphane

methyl iodide

Acetylmethylphenylphosphanoxid

Downstream raw materials:

Dimethylaminomethyl-methylphenylphosphin

methylphenylphosphinic acid

(Ethoxy-phenyl-methyl)-methyl-phenyl-phosphane

(Butoxy-phenyl-methyl)-methyl-phenyl-phosphane