diphenyl(N,N-dimethylaminoethylferrocenyl)stibine

Base Information

• Chemical Name: diphenyl(N,N-dimethylaminoethylferrocenyl)stibine
• CAS No.: 911852-59-0
• Molecular Formula: C₂₆H₂₈FeNSb
• Molecular Weight: 532.112
• Mol file: 911852-59-0.mol

Synonyms:

Chemical Property of diphenyl(N,N-dimethylaminoethylferrocenyl)stibine

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of diphenyl(N,N-dimethylaminoethylferrocenyl)stibine

There total 1 articles about diphenyl(N,N-dimethylaminoethylferrocenyl)stibine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 55.0%

2-lithium-(N,N-dimethylaminoethyl)ferrocene + diphenylantimony(III) chloride (2629-47-2) → diphenyl(N,N-dimethylaminoethylferrocenyl)stibine (911852-59-0)

Guidance literature:

In tetrahydrofuran; compds. reacted in Schlenk tube under N2 atm.; soln. of Sb compd. in anhydrous THF added dropwise to Fe compd. (prepd. in situ) at -20°C with continuous stirring, mixt. stirred for 24 h at room temp.; react. mixt. quenched on ice, extd. with CH2Cl2, dried over Na2SO4, solvent removed in vac. (slowly concd.);

DOI:10.1016/j.inoche.2005.09.029

Reference yield: 95.0%

diphenyl(N,N-dimethylaminoethylferrocenyl)stibine (911852-59-0) + methyl iodide (74-88-4) → diphenyl(2-vinylferrocenyl)stibine (947499-11-8)

Guidance literature:

In chloroform; (under N2, Schlenk); CH3I added to soln. of FeSb-complex in CHCl3 with stirring, stirred for 2 h; concd. in vac., ppt. filtered, dried, recrystd. from chloroform;

DOI:10.1016/j.jorganchem.2007.04.020

upstream raw materials:

diphenylantimony(III) chloride

Downstream raw materials:

diphenyl(2-vinylferrocenyl)stibine