(C(CH₃)3C₆H₄)4C₂₀H₆N₄NiNH₂NHCOH

Base Information

• Chemical Name: (C(CH₃)3C₆H₄)4C₂₀H₆N₄NiNH₂NHCOH
• CAS No.: 944133-12-4
• Molecular Formula: C₆₁H₆₂N₆NiO
• Molecular Weight: 953.893
• Mol file: 944133-12-4.mol

Synonyms:

Chemical Property of (C(CH₃)3C₆H₄)4C₂₀H₆N₄NiNH₂NHCOH

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

Useful:

Technology Process of (C(CH₃)3C₆H₄)4C₂₀H₆N₄NiNH₂NHCOH

There total 2 articles about (C(CH₃)3C₆H₄)4C₂₀H₆N₄NiNH₂NHCOH which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 58.0%

formic acid (64-18-6) + (C(CH3)3C6H4)4C20H6N4Ni(NH2)2 → (C(CH3)3C6H4)4C20H6N4NiNH2NHCOH (944133-12-4)

Guidance literature:

formic acid; (C(CH₃)3C₆H₄)4C₂₀H₆N₄Ni(NH₂)2; In toluene; for 2h; Reflux; Inert atmosphere;

With potassium carbonate; In toluene;

DOI:10.1002/ejoc.200901310

Reference yield:

sodium tetrahydroborate (16940-66-2) + formic acid (64-18-6) + (C(CH3)3C6H4)4C20H6N4NiNO2NH2 (944133-11-3) → (C(CH3)3C6H4)4C20H6N4NiCHN2H (944133-08-8) + (C(CH3)3C6H4)4C20H6N4NiNH2NHCOH (944133-12-4) + (C(CH3)3C6H4)4C20H6N4Ni(NHCOH)2 (944133-13-5)

Guidance literature:

With Pd/C; In methanol; dichloromethane; toluene; Ni complex reacted with NaBH4 in CH2Cl2/CH3OH in the presence of Pd/C at25°C for 1 h, treated with formic acid in toluene (1:1), refluxe d for 10 min at 110°C; chromy.(silica gel);

DOI:10.1039/b704681b

Reference yield:

(C(CH3)3C6H4)4C20H6N4NiNH2NHCOH (944133-12-4) → (C(CH3)3C6H4)4C20H6N4NiCHN2H (944133-08-8)

Guidance literature:

With trifluoroacetic acid; In toluene; trifluoroacetic acid and Ni complex refluxed at 110°C for 3 h in toluene;

DOI:10.1039/b704681b

upstream raw materials:

sodium tetrahydroborate

formic acid

(C(CH₃)3C₆H₄)4C₂₀H₆N₄NiNO₂NH₂

Downstream raw materials:

(C(CH₃)3C₆H₄)4C₂₀H₆N₄NiCHN₂H