(η1:η6.-(2-phenyl-1-dicyclohexylphosphinoethane))ruthenium(II) dichloride

Base Information

Chemical Name:(η1:η6.-(2-phenyl-1-dicyclohexylphosphinoethane))ruthenium(II) dichloride
CAS No.:307933-36-4
Molecular Formula:C₂₀H₃₁Cl₂PRu
Molecular Weight:474.416
Hs Code.:

Synonyms:

Suppliers and Price of (η1:η6.-(2-phenyl-1-dicyclohexylphosphinoethane))ruthenium(II) dichloride

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of (η1:η6.-(2-phenyl-1-dicyclohexylphosphinoethane))ruthenium(II) dichloride

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of (η1:η6.-(2-phenyl-1-dicyclohexylphosphinoethane))ruthenium(II) dichloride

There total 1 articles about (η1:η6.-(2-phenyl-1-dicyclohexylphosphinoethane))ruthenium(II) dichloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 94.0%

: 577969-98-3
(p-cymene)Ru(PCy₂CH₂CH₂C₆H₅)Cl₂

: 307933-36-4
(η1:η6.-(2-phenyl-1-dicyclohexylphosphinoethane))ruthenium(II) dichloride

Guidance literature:: In chlorobenzene; byproducts: p-cymene; under Ar; Ru complex refluxed in degassed chlorobenzene for 6 h; filtered; crystals washed with hexanes and Et2O; filtrate again refluxed, crystals collected; repeated three times; crystals washed with hexanesand Et2O; dried under vac.; elem. anal.;
DOI:10.1021/om0300070

Reference yield: 37.0%

: 307933-36-4
(η1:η6.-(2-phenyl-1-dicyclohexylphosphinoethane))ruthenium(II) dichloride

: 917-54-4
methyllithium

: 577969-94-9
(η6:η1-C6H5CH2CH2PCy2)Ru(CH3)2

Guidance literature:: In diethyl ether; Ru complex suspended in dry Et2O; MeLi (6.2 equiv.) added at -78°C; warmed gradually to room temp.; stirred for 1 h; solvent evapd.; extd. with benzene; solvent evapd.; purified by column chromy. (Al2O3, Et2O); yellow fractions collected; crystd. by slow evapn.of solvent; elem. anal.;
DOI:10.1021/om0300070

Reference yield:

: 14104-20-2
silver tetrafluoroborate

: 307933-36-4
(η1:η6.-(2-phenyl-1-dicyclohexylphosphinoethane))ruthenium(II) dichloride

: (η1:η6.-(2-phenyl-1-dicyclohexylphosphinoethane))ruthenium(II)(BF4)2

Guidance literature:: In chloroform-d1; byproducts: AgCl; (Ar), mixed with stirring for 10 min; AgCl filtered off, not isolated, detected by NMR;
DOI:10.1016/S1381-1169(00)00229-6