[(η5-cyclopentadienyl)Ru(carbonyl)(PPh2CH2PPh2)I]

Base Information

• Chemical Name: [(η5-cyclopentadienyl)Ru(carbonyl)(PPh2CH2PPh2)I]
• CAS No.: 95419-97-9
• Molecular Formula: C₃₁H₂₇IOP₂Ru
• Molecular Weight: 705.477
• Mol file: 95419-97-9.mol

Synonyms:

Chemical Property of [(η5-cyclopentadienyl)Ru(carbonyl)(PPh2CH2PPh2)I]

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [(η5-cyclopentadienyl)Ru(carbonyl)(PPh2CH2PPh2)I]

There total 4 articles about [(η5-cyclopentadienyl)Ru(carbonyl)(PPh2CH2PPh2)I] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 70.1%

iodo(cyclopentadienyl)dicarbonylruthenium(II) + bis-diphenylphosphinomethane (2071-20-7) → [(η5-cyclopentadienyl)Ru(carbonyl)(PPh2CH2PPh2)I] (95419-97-9,95419-94-6)

Guidance literature:

In benzene; under Ar; soln. of Ru complex and ligand in benzene refluxed for 12 h; solvent removed under vac.; purified by column chromy. (silica gel, CH2Cl2); elem. anal.;

DOI:10.1021/om0610750

Reference yield:

iodo(cyclopentadienyl)dicarbonylruthenium(II) + bis-diphenylphosphinomethane (2071-20-7) → [(η5-cyclopentadienyl)Ru(carbonyl)(PPh2CH2PPh2)]I (95419-94-6,95419-97-9) + [(η5-cyclopentadienyl)Ru(carbonyl)(PPh2CH2PPh2)I] (95419-97-9,95419-94-6)

Guidance literature:

pentamethylcyclopentadienyliron(III) dicarbonyl dimer; In toluene; under N2; soln. of Ru complex and 1 equiv of ligand in toluene heated to 105-110 °C, added catalyst, completion of react. detected by IRand TLC (SiO2, toluene); (CpRu(CO)(Ph2PCH2PPh2))I filtered, washed with toluene, recrystd. from CH2Cl2/hexane; (CpRuI(CO)(Ph2PCH2PPh2)) sepd. by chromy. (SiO2, benzene)of filtrate; elem. anal.;

DOI:10.1016/0022-328X(84)80685-3

Reference yield:

iodo(cyclopentadienyl)dicarbonylruthenium(II) + bis-diphenylphosphinomethane (2071-20-7) → [(η5-cyclopentadienyl)Ru(carbonyl)(PPh2CH2PPh2)]I (95419-94-6,95419-97-9) + [(η5-cyclopentadienyl)Ru(carbonyl)(PPh2CH2PPh2)I] (95419-97-9,95419-94-6)

Guidance literature:

pentamethylcyclopentadienyliron(III) dicarbonyl dimer; In toluene; under N2; soln. of Ru complex and 1 equiv of ligand in toluene heated to 105-110 °C, added catalyst, completion of react. detected by IRand TLC (SiO2, toluene); (CpRu(CO)(Ph2PCH2PPh2))I filtered, washed with toluene, recrystd. from CH2Cl2/hexane; (CpRuI(CO)(Ph2PCH2PPh2)) sepd. by chromy. (SiO2, benzene)of filtrate; elem. anal.;

DOI:10.1016/0022-328X(84)80685-3

upstream raw materials:

[(η5-cyclopentadienyl)Ru(carbonyl)(PPh2CH2PPh2)I]

bis-diphenylphosphinomethane

Downstream raw materials:

[(η5-cyclopentadienyl)Ru(carbonyl)(PPh2CH2PPh2)]I

[(cyclopentadienyl)Ru(CO)(μ-bis(diphenylphosphino)methane)(μ-I)PdI2]

[(cyclopentadienyl)Ru(CO)(μ-bis(diphenylphosphino)methane)(μ-I)PtI2]

cis-diiodo[1,1'-methylenebis[1,1-diphenylphosphine-κP]]platinum