N,N'-Bis(2-hydroxyphenyl)-1,2-diphenyl-1,2-ethanediimine

Base Information

• Chemical Name: N,N'-Bis(2-hydroxyphenyl)-1,2-diphenyl-1,2-ethanediimine
• CAS No.: 120972-67-0
• Molecular Formula: C₂₆H₂₀N₂O₂
• Molecular Weight: 392.457
• DSSTox Substance ID: DTXSID801183152
• Nikkaji Number: J1.297.720D
• Mol file: 120972-67-0.mol

Synonyms:N,N'-Bis(2-hydroxyphenyl)-1,2-diphenyl-1,2-ethanediimine;DTXSID801183152;AQ-008/41080141;2,2'-[(1,2-Diphenyl-1,2-ethanediylidene)dinitrilo]bis[phenol];2-({2-[(2-hydroxyphenyl)imino]-1,2-diphenylethylidene}amino)phenol;2-[[2-(2-hydroxyphenyl)imino-1,2-diphenylethylidene]amino]phenol;6-[(Z)-2-(2-hydroxyanilino)-1,2-diphenylethenyl]iminocyclohexa-2,4-dien-1-one;120972-67-0

Chemical Property of N,N'-Bis(2-hydroxyphenyl)-1,2-diphenyl-1,2-ethanediimine

Chemical Property:

• PSA: 65.18000
• LogP: 6.03960
• XLogP3: 5.9
• Hydrogen Bond Donor Count: 2
• Hydrogen Bond Acceptor Count: 4
• Rotatable Bond Count: 5
• Exact Mass: 392.152477885
• Heavy Atom Count: 30
• Complexity: 538

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

• Canonical SMILES: C1=CC=C(C=C1)C(=NC2=CC=CC=C2O)C(=NC3=CC=CC=C3O)C4=CC=CC=C4

Technology Process of N,N'-Bis(2-hydroxyphenyl)-1,2-diphenyl-1,2-ethanediimine

There total 1 articles about N,N'-Bis(2-hydroxyphenyl)-1,2-diphenyl-1,2-ethanediimine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

2-amino-phenol (95-55-6) + benzil (134-81-6) → 3,4-dihydro-2,3-diphenyl-2H-benzo[b][1,4]oxazine + bis(aminophenol)benzil (120972-67-0) + C26H24N2O2 (95667-20-2)

Guidance literature:

With sodium hydroxide; borane; Yield given. Multistep reaction. Yields of byproduct given; 1.) THF, RT;

Reference yield: 71.0%

[ruthenium(II)(hydride)(chloride)(carbonyl)(triphenylarsine)3] (75455-74-2,130061-85-7) + bis(2-hydroxyanil)benzil (120972-67-0) → Ru(CO)(As(C6H5)3)((O)C6H4NC(C6H5))2 (927827-85-8)

Guidance literature:

In benzene; to Ru-compd. in benzene added phenol-compd. with molar ratio 1:1, heatedunder reflux for 6 h; concentrated, light petroleum added, filtered, washed with light petroleum, recrystallized from CH2Cl2/light petroleum (60-80°C), dried in vac., elem. anal.;

DOI:10.1080/15533170600732619

Reference yield: 71.0%

(carbonyl)(chloro)(hydrido)tris(triphenylphosphine)ruthenium(II) (157072-60-1,61521-25-3,166941-05-5,16971-33-8) + bis(2-hydroxyanil)benzil (120972-67-0) → Ru(CO)(P(C6H5)3)((O)C6H4NC(C6H5))2 (927827-82-5)

Guidance literature:

In benzene; to Ru-compd. in benzene added phenol-compd. with molar ratio 1:1, heatedunder reflux for 6 h; concentrated, light petroleum added, filtered, washed with light petroleum, recrystallized from CH2Cl2/light petroleum (60-80°C), dried in vac., elem. anal.;

DOI:10.1080/15533170600732619

upstream raw materials:

2-amino-phenol

benzil

Downstream raw materials:

Ru(CO)(As(C₆H₅)3)((O)C₆H₄NC(C₆H₅))2

Ru(CO)(P(C₆H₅)3)((O)C₆H₄NC(C₆H₅))2

Ru(CO)(C₅H₅N)((O)C₆H₄NC(C₆H₅))2

(bis(2-oxyanil)benzil)manganese(II)