Pt6(μ6-Hg)(μ-CO)6(CO)2(μ-dpppe)2

Base Information

• Chemical Name: Pt6(μ6-Hg)(μ-CO)6(CO)2(μ-dpppe)2
• CAS No.: 178115-42-9
• Molecular Formula: C₆₆H₆₀HgO₈P₄Pt₆
• Molecular Weight: 2476.16
• Mol file: 178115-42-9.mol

Synonyms:

Chemical Property of Pt6(μ6-Hg)(μ-CO)6(CO)2(μ-dpppe)2

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
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MSDS Files:

Useful:

Technology Process of Pt6(μ6-Hg)(μ-CO)6(CO)2(μ-dpppe)2

There total 1 articles about Pt6(μ6-Hg)(μ-CO)6(CO)2(μ-dpppe)2 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 76.0%

dichlorobis(dimethylsulfide)platinum(II) (17457-51-1,17836-09-8,55449-91-7) + carbon monoxide (201230-82-2) + 1,5-bis-(diphenylphosphino)pentane (27721-02-4) + mercury → Pt6(μ6-Hg)(μ-CO)6(CO)2(μ-dpppe)2 (178115-42-9) + Pt6(μ6-Hg)(μ-CO)6(μ-dpppe)3

Guidance literature:

With NaBH₄; In tetrahydrofuran; methanol; N2-atmosphere; addn. of phosphine to THF soln. of Pt-complex, saturationwith CO, addn. of NaBH4, stirring for 8 h under CO, addn. of MeOH, stir ring overnight under CO, addn. of 1 equiv. of TlPF6, stirring for 48 h under CO; evapn., extn. (CH2Cl2), filtration (Celite), evapn.; NMR spectroscopy;

DOI:10.1021/om960148k

Reference yield: 82.0%

Pt6(μ6-Hg)(μ-CO)6(CO)2(μ-dpppe)2 (178115-42-9) + 1,5-bis-(diphenylphosphino)pentane (27721-02-4) → Pt6(μ6-Hg)(μ-CO)6(μ-dpppe)3

Guidance literature:

In dichloromethane; N2-atmosphere; slight excess of phosphine, stirring for O.5 h; evapn., recrystn. (CH2Cl2:hexane); elem. anal.;

DOI:10.1021/om960148k

upstream raw materials:

dichlorobis(dimethylsulfide)platinum(II)

carbon monoxide

1,5-bis-(diphenylphosphino)pentane