(Pd(Cl)(C₆H₄CH₃NCHC₆H₃CH₃))2

Base Information

• Chemical Name: (Pd(Cl)(C₆H₄CH₃NCHC₆H₃CH₃))2
• CAS No.: 103957-15-9
• Molecular Formula: C₃₀H₂₈Cl₂N₂Pd₂
• Molecular Weight: 700.312
• Mol file: 103957-15-9.mol

Synonyms:

Chemical Property of (Pd(Cl)(C₆H₄CH₃NCHC₆H₃CH₃))2

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (Pd(Cl)(C₆H₄CH₃NCHC₆H₃CH₃))2

There total 1 articles about (Pd(Cl)(C₆H₄CH₃NCHC₆H₃CH₃))2 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

(Pd(CH3COO)(C6H4CH3NCHC6H3CH3))2 (94399-00-5) + lithium chloride → (Pd(Cl)(C6H4CH3NCHC6H3CH3))2 (103957-15-9,22338-13-2)

Guidance literature:

In water; acetone; aq. soln. of LiCl is added dropwise to a soln. of Pd-compd. in acetone,stirring for 30 min at room temp.; filtn., washing twice with acetone, drying,elem. anal.;

DOI:10.1002/hlca.19850680730

Reference yield: 94.0%

pyridine (110-86-1) + (Pd(Cl)(C6H4CH3NCHC6H3CH3))2 (103957-15-9,22338-13-2) → (Pd(Cl)(C6H4CH3NCHC6H3CH3)(C5H5N)) (103781-25-5)

Guidance literature:

In dichloromethane; addn. of pyridine to a suspn. of Pd-compd. in CH2Cl2, stirring at room temp. for 5 min, precipitating with petroleum ether; filtn., drying, elem. anal.;

DOI:10.1002/hlca.19850680730

Reference yield: 90.0%

(Pd(Cl)(C6H4CH3NCHC6H3CH3))2 (103957-15-9,22338-13-2) + silver trifluoromethanesulfonate (2923-28-6) + 2,2'-bis-(diphenylphosphino)-1,1'-binaphthyl (76144-87-1,76189-55-4,76189-56-5,136655-44-2,98327-87-8) → (CH3C6H4NCHC6H3CH3)Pd(P(C6H5)2C20H12P(C6H5)2)(1+)*CF3SO3(1-)=(C15H14N)Pd(P2(C6H5)4C20H12)(CF3SO3) (952488-10-7)

Guidance literature:

In dichloromethane; (N2) to 1 equiv of Pd-complex were added 2 equiv of BINAP and 2 equiv ofCF3SO3Ag in CH2Cl2, the mixt. was stirred at 25°C for 3 h; sepd., reduced in vac.; elem. anal.;

DOI:10.1021/om700299b

upstream raw materials:

(Pd(CH₃COO)(C₆H₄CH₃NCHC₆H₃CH₃))2

Downstream raw materials:

(CH₃C₆H₄NCHC₆H₃CH₃)Pd(P(C₆H₅)2C₂₀H₁₂P(C₆H₅)2)⁽¹⁺⁾*CF₃SO₃^(1-)=(C₁₅H₁₄N)Pd(P₂(C₆H₅)4C₂₀H₁₂)(CF₃SO₃)

(Pd(Cl)(C₆H₄CH₃NCHC₆H₃CH₃)(C₅H₅N))