{dioxouranium(VI)(benzilbis(benzoylhydrazone))(sulphate)}

Base Information

• Chemical Name: {dioxouranium(VI)(benzilbis(benzoylhydrazone))(sulphate)}
• CAS No.: 125955-29-5
• Molecular Formula: C₂₈H₂₂N₄O₈SU
• Molecular Weight: 812.6
• Mol file: 125955-29-5.mol

Synonyms:

Chemical Property of {dioxouranium(VI)(benzilbis(benzoylhydrazone))(sulphate)}

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of {dioxouranium(VI)(benzilbis(benzoylhydrazone))(sulphate)}

There total 3 articles about {dioxouranium(VI)(benzilbis(benzoylhydrazone))(sulphate)} which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

{UO2(C6H5C(O)NNC(C6H5)C(C6H5)NNC(O)C6H5)(H2O)2} → {dioxouranium(VI)(benzilbis(benzoylhydrazone))(sulphate)} (125955-29-5)

Guidance literature:

With H₂SO₄; In ethanol; stirring a suspension of compd. in dry EtOH for 2 h in presence of the corresponding acid at pH1-2;

Reference yield:

hydrated uranyl sulphate + benzil bis(benzoylhydrazone) (36289-76-6) → {dioxouranium(VI)(benzilbis(benzoylhydrazone))(sulphate)} (125955-29-5)

Guidance literature:

In methanol; ethanol; hydrated metal salt in MeOH/EtOH was added to a well stirred suspension of the ligand in EtOH (molar ratio 1,25:1), pH of the soln. was adjusted to 1-2 by adding of the corresponding acid, mixture was stirred for 1-2 h; yellow to orange-red complex was filtered, washed with EtOH and dried over fused CaCl2, elem. anal.;

Reference yield:

{dioxouranium(VI)(benzoylhydrazide)2(sulphate)} + benzil (134-81-6) → {dioxouranium(VI)(benzilbis(benzoylhydrazone))(sulphate)} (125955-29-5)

Guidance literature:

In ethanol; stirring a suspension in EtOH of the corresponding uranyl complex of benzoylhydrazide with benzil (molar ratio 1:1,25) for 1-2 h at 20°C;

upstream raw materials:

benzil bis(benzoylhydrazone)

benzil