Pentanethioic acid, 3-hydroxy-2,4-dimethyl-, S-phenyl ester, (2S,3R)-

Base Information

• Chemical Name: Pentanethioic acid, 3-hydroxy-2,4-dimethyl-, S-phenyl ester, (2S,3R)-
• CAS No.: 121788-81-6
• Molecular Formula: C₁₃H₁₈O₂S
• Molecular Weight: 238.351
• Mol file: 121788-81-6.mol

Synonyms:

Chemical Property of Pentanethioic acid, 3-hydroxy-2,4-dimethyl-, S-phenyl ester, (2S,3R)-

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Pentanethioic acid, 3-hydroxy-2,4-dimethyl-, S-phenyl ester, (2S,3R)-

There total 1 articles about Pentanethioic acid, 3-hydroxy-2,4-dimethyl-, S-phenyl ester, (2S,3R)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

S-phenylthiopropionate (18245-72-2) + isobutyraldehyde (78-84-2) → 3-Hydroxy-2,4-dimethyl-pentanethioic acid S-phenyl ester (342892-46-0) + (2S,3R)-3-Hydroxy-2,4-dimethyl-pentanethioic acid S-phenyl ester (121788-81-6)

Guidance literature:

With (R,R)-bromoborane 17; N-ethyl-N,N-diisopropylamine; Yield given. Multistep reaction. Yields of byproduct given. Title compound not separated from byproducts; 1.) CH₂Cl₂, -45 deg C;

DOI:10.1021/ja00196a081

upstream raw materials:

S-phenylthiopropionate

isobutyraldehyde

Refernces