methyl 4,5-dibromo-3-methyl-2-furancarboxylate

Base Information

Chemical Name:methyl 4,5-dibromo-3-methyl-2-furancarboxylate
CAS No.:441016-68-8
Molecular Formula:C₇H₆Br₂O₃
Molecular Weight:297.931
Hs Code.:

Synonyms:

Suppliers and Price of methyl 4,5-dibromo-3-methyl-2-furancarboxylate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
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Total 2 raw suppliers

Chemical Property of methyl 4,5-dibromo-3-methyl-2-furancarboxylate

Chemical Property:

Purity/Quality:: 99%, ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Technology Process of methyl 4,5-dibromo-3-methyl-2-furancarboxylate

There total 1 articles about methyl 4,5-dibromo-3-methyl-2-furancarboxylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 6141-57-7
methyl 3-methylfuran-2-carboxylate

: 2528-01-0
5-bromo-3-methylfuran-2-carboxylic acid methyl ester

: 441016-68-8
methyl 4,5-dibromo-3-methyl-2-furancarboxylate

Guidance literature:: With bromine;
DOI:10.1039/P19810000679

Reference yield:

: 441016-68-8
methyl 4,5-dibromo-3-methyl-2-furancarboxylate

: 441016-49-5
3-ethynyl-4-methyl-furan-2-carbaldehyde

Guidance literature:: Multi-step reaction with 4 steps

1.1: sodium hydroxide / H₂O / 16 h / Heating

2.1: 74 percent / copper; quinoline / 42 h / 170 - 180 °C

3.1: n-butyllithium / diethyl ether; hexane / 0.5 h / -78 °C

3.2: 70 percent / diethyl ether; hexane / 1.5 h / -78 - 20 °C

4.1: 87 percent / triphenylphosphine; triethylamine; cuprous iodide / (PPh₃)PdCl₂ / tetrahydrofuran / 20 °C

With quinoline; sodium hydroxide; copper(l) iodide; n-butyllithium; copper; triethylamine; triphenylphosphine; (PPh₃)PdCl₂; In tetrahydrofuran; diethyl ether; hexane; water;
DOI:10.1021/jo011136y