Aluminum,methylbis([1,1':3',1''-terphenyl]-2'-olato)-

Base Information

• Chemical Name: Aluminum,methylbis([1,1':3',1''-terphenyl]-2'-olato)-
• CAS No.: 118496-00-7
• Molecular Formula: C37H29 Al O2
• Molecular Weight: 532.618
• Mol file: 118496-00-7.mol

Synonyms:[1,1':3',1''-Terphenyl]-2'-ol,aluminum complex; MAPh; Methylaluminum bis(2,6-diphenylphenoxide)

Chemical Property of Aluminum,methylbis([1,1':3',1''-terphenyl]-2'-olato)-

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Aluminum,methylbis([1,1':3',1''-terphenyl]-2'-olato)-

There total 2 articles about Aluminum,methylbis([1,1':3',1''-terphenyl]-2'-olato)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

(1,1';3',1''-terphenyl)-2'-ol (2432-11-3) + trimethylaluminum (75-24-1) → methylaluminium bis(2,6-diphenylphenoxide) (118496-00-7)

Guidance literature:

In dichloromethane; byproducts: CH4; to soln. of the phenol (2 equiv in CH2Cl2) added Me3Al (1 equiv in hexane, room temp.), stirred at room temp. for 1h; alternatively toluene as solvent; not isolated;

Reference yield:

trimethylaluminium dimer + (1,1';3',1''-terphenyl)-2'-ol (2432-11-3) → methylaluminium bis(2,6-diphenylphenoxide) (118496-00-7)

Guidance literature:

In toluene; prepn. from Me3Al and 2,6-diphenylphenol in degassed toluene at room temp. for 1 h under Ar; not isolated from soln.;

DOI:10.1246/bcsj.65.541

Reference yield:

1,3,5-Trioxan (110-88-3) + methylaluminium bis(2,6-diphenylphenoxide) (118496-00-7) → C37H29AlO2*CH2O

Guidance literature:

In hexane; dichloromethane; at 0 ℃; for 1h;

DOI:10.1021/ja00063a013

upstream raw materials:

(1,1';3',1''-terphenyl)-2'-ol

trimethylaluminum

Downstream raw materials:

(CH₂O)Al(CH₃)(O(C₆H₃)(C₆H₅)2)2

(CH₃CH₂CH₂CHO)Al(CH₃)(O(C₆H₃)(C₆H₅)2)2

((C₆H₅)2C₆H₃O)2AlN(CF₃SO₂)2