[Rh(CO)(CH₃CN)(Ph₂PCH₂C(Ph)=N(2,6-Me₂C₆H₃))]BF₄

Base Information

• Chemical Name: [Rh(CO)(CH₃CN)(Ph₂PCH₂C(Ph)=N(2,6-Me₂C₆H₃))]BF₄
• CAS No.: 850879-76-4
• Molecular Formula: BF₄*C₃₁H₂₉N₂OPRh
• Molecular Weight: 666.268
• Mol file: 850879-76-4.mol

Synonyms:

Chemical Property of [Rh(CO)(CH₃CN)(Ph₂PCH₂C(Ph)=N(2,6-Me₂C₆H₃))]BF₄

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [Rh(CO)(CH₃CN)(Ph₂PCH₂C(Ph)=N(2,6-Me₂C₆H₃))]BF₄

There total 1 articles about [Rh(CO)(CH₃CN)(Ph₂PCH₂C(Ph)=N(2,6-Me₂C₆H₃))]BF₄ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 62.0%

[Ph2PCH2C(Ph)=N(2,6-Me2C6H3)] + silver tetrafluoroborate (14104-20-2) + di(rhodium)tetracarbonyl dichloride + acetonitrile (75-05-8,26809-02-9) → [Rh(CO)(CH3CN)(Ph2PCH2C(Ph)=N(2,6-Me2C6H3))]BF4 (850879-76-4)

Guidance literature:

In acetonitrile; (Ar); std. Schlenk technique; AgBF4 (2 equiv.) was added to soln. of Rh complex (1 equiv.) in CH3CN; mixt. was stirred at room temp.; filtered; soln. of ligand (2 equiv.) in CH3CN was added with stirring; mixt. was stirred for 10 h at room temp.; solvent removed (vac.); residue washed (cold C6H6/pentane, 1/4); recrystd. (CH2Cl2/pentane, 1/4); elem. anal.;

DOI:10.1016/j.jorganchem.2005.01.016

Reference yield: 69.0%

[Ph2PCH2C(Ph)=N(2,6-Me2C6H3)] + [Rh(CO)(CH3CN)(Ph2PCH2C(Ph)=N(2,6-Me2C6H3))]BF4 (850879-76-4) → cis-[Rh(Ph2PCH2C(Ph)=N(2,6-Me2C6H3))2]BF4 (850879-78-6)

Guidance literature:

In dichloromethane; (Ar); std. Schlenk technique; CH2Cl2 was added dropwise to mixt. of Rh complex and ligand (1 equiv.); mixt. was stirred for 10 h; volatiles removed (vac.); recrystd. (CH2Cl2/pentane, 1/4, -20°C);

DOI:10.1016/j.jorganchem.2005.01.016

upstream raw materials:

silver tetrafluoroborate

acetonitrile

Downstream raw materials:

cis-[Rh(Ph₂PCH₂C(Ph)=N(2,6-Me₂C₆H₃))2]BF₄