1-Benzyl-8--6,9-dimethyl-2,5-dioxo-1,2,3,4,5,6-hexahydro-1-benzazocine

Base Information

• Chemical Name: 1-Benzyl-8--6,9-dimethyl-2,5-dioxo-1,2,3,4,5,6-hexahydro-1-benzazocine
• CAS No.: 88589-39-3
• Molecular Formula: C₃₄H₃₄N₂O₄S
• Molecular Weight: 566.721

Synonyms:

Chemical Property of 1-Benzyl-8--6,9-dimethyl-2,5-dioxo-1,2,3,4,5,6-hexahydro-1-benzazocine

Chemical Property:

Purity/Quality:

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Useful:

Technology Process of 1-Benzyl-8--6,9-dimethyl-2,5-dioxo-1,2,3,4,5,6-hexahydro-1-benzazocine

There total 4 articles about 1-Benzyl-8--6,9-dimethyl-2,5-dioxo-1,2,3,4,5,6-hexahydro-1-benzazocine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 32.0%

2,5-Bis-4-(2,5-dioxo-1-methylcyclopentyl)toluene (88589-36-0) → 4-Benzyl-7--6,8b-dimethyl-3a-hydroxy-1-oxo-1,2,3,3a,4,8b-hexahydrocyclopentindole (88589-37-1) + 1-Benzyl-8--6,9-dimethyl-2,5-dioxo-1,2,3,4,5,6-hexahydro-1-benzazocine (88589-39-3) + 1-Benzyl-8-(benzylamino)-6,9-dimethyl-2,5-dioxo-1,2,3,4,5,6-hexahydro-1-benzazocine (88609-66-9)

Guidance literature:

With anthracene; N,N,N,N-tetraethylammonium tetrafluoroborate; In N,N-dimethyl-formamide; for 0.133333h; electrolysis with Hg cathode at -2.00 V vs. Pt, carbon rod as anode;

DOI:10.1021/jo00180a001

Reference yield:

C27H28N2O6S2 (72374-10-8) → 1-Benzyl-8--6,9-dimethyl-2,5-dioxo-1,2,3,4,5,6-hexahydro-1-benzazocine (88589-39-3)

Guidance literature:

Multi-step reaction with 2 steps

1: 98 percent / K₂CO₃, KI / acetone / 72 h / Heating

2: dimethylformamide / Ambient temperature; electrolysis with Hg cathode, carbon rod as anode, SCE as reference

With potassium carbonate; potassium iodide; In N,N-dimethyl-formamide; acetone;

DOI:10.1021/jo00180a001

Reference yield:

benzyl bromide (100-39-0) → 1-Benzyl-8--6,9-dimethyl-2,5-dioxo-1,2,3,4,5,6-hexahydro-1-benzazocine (88589-39-3)

Guidance literature:

Multi-step reaction with 2 steps

1: 98 percent / K₂CO₃, KI / acetone / 72 h / Heating

2: dimethylformamide / Ambient temperature; electrolysis with Hg cathode, carbon rod as anode, SCE as reference

With potassium carbonate; potassium iodide; In N,N-dimethyl-formamide; acetone;

DOI:10.1021/jo00180a001

upstream raw materials:

2,5-Bis-4-(2,5-dioxo-1-methylcyclopentyl)toluene

C₂₇H₂₈N₂O₆S₂

benzyl bromide

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