25,26,27,28-tetrapropyloxycalix[4]arene

Base Information

• Chemical Name: 25,26,27,28-tetrapropyloxycalix[4]arene
• CAS No.: 140862-52-8
• Molecular Formula: C₄₀H₄₈O₄
• Molecular Weight: 592.819
• Mol file: 140862-52-8.mol

Synonyms:

Chemical Property of 25,26,27,28-tetrapropyloxycalix[4]arene

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 25,26,27,28-tetrapropyloxycalix[4]arene

There total 17 articles about 25,26,27,28-tetrapropyloxycalix[4]arene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

25,26,27,28-tetrakis(hydroxy)calix[4]arene (248590-47-8,74568-07-3) + 1-iodo-propane (107-08-4) → 25,26,27,28-tetrapropyloxycalix[4]arene (140862-52-8,140924-91-0,141902-33-2,143444-60-4,147782-22-7)

Guidance literature:

With sodium hydride;

DOI:10.1142/S1088424610002525

Reference yield: 93.0%

25,26,27,28-tetrakis(hydroxy)calix[4]arene (248590-47-8,74568-07-3) → 25,26,27,28-tetrapropyloxycalix[4]arene (140862-52-8,140924-91-0,141902-33-2,143444-60-4,147782-22-7)

Guidance literature:

25,26,27,28-tetrakis(hydroxy)calix[4]arene; With sodium hydride; In N,N-dimethyl-formamide; at 70 ℃; for 0.25h;

propyl halide; at 70 ℃; for 1h;

DOI:10.1007/s10847-012-0273-y

Reference yield: 92.0%

25,26,27,28-tetrakis(hydroxy)calix[4]arene (248590-47-8,74568-07-3) + propyl bromide (106-94-5) → 25,26,27,28-tetrapropyloxycalix[4]arene (140862-52-8,140924-91-0,141902-33-2,143444-60-4,147782-22-7)

Guidance literature:

25,26,27,28-tetrakis(hydroxy)calix[4]arene; With sodium hydride; In N,N-dimethyl-formamide; mineral oil; at 0 ℃; for 0.5h; Schlenk technique; Inert atmosphere;

propyl bromide; In N,N-dimethyl-formamide; mineral oil; at 20 ℃; for 8h; Schlenk technique; Inert atmosphere;

DOI:10.1021/ja503506a

upstream raw materials:

25,26,27,28-tetrakis(hydroxy)calix[4]arene

propyl bromide

propyl tosylate

25,27-dihydroxy-26,28-dipropoxycalix[4]arene

Downstream raw materials:

5,11,17,23-tetrakis(chloromethyl)-25,26,27,28-tetrapropoxycalix[4]arene

5,11,17,23-tetrabromo-25,26,27,28-tetrapropoxycalix[4]arene

cone-25,26,27,28-tetrapropoxycalix{4}arene-tricarbonylchromium

chromium(III) chloride

Refernces

• 1、 Ka?áková, Martina,Malinovská, Lenka,Klejch, Tomá?,Hlavá?ková, Martina,Dvo?áková, Hana,Fujdiarová, Eva,Rottnerová, Zdeňka,Ma?átková, Olga,Lhoták, Pavel,Wimmerová, Michaela,Moravcová, Jitka. "Selectivity of original C-hexopyranosyl calix[4]arene conjugates towards lectins of different origin". . p. 60 - 72. Retrieved 2018/10/15.
• 2、 Zairov, Rustem,Shamsutdinova, Nataliya,Podyachev, Sergey,Sudakova, Svetlana,Gimazetdinova, Gulnaz,Rizvanov, Ildar,Syakaev, Victor,Babaev, Vasily,Amirov, Rustem,Mustafina, Asiya. "Structure impact in antenna effect of novel upper rim substituted tetra-1,3-diketone calix[4]arenes on Tb(III) green and Yb(III) NIR-luminescence". . p. 2447 - 2455. Retrieved 2016/04/26.