2-(2',6'-difluorophenyl)-1,10-phenanthroline

Base Information

Chemical Name:2-(2',6'-difluorophenyl)-1,10-phenanthroline
CAS No.:1272029-49-8
Molecular Formula:C₁₈H₁₀F₂N₂
Molecular Weight:292.288
Hs Code.:

Synonyms:

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of 2-(2',6'-difluorophenyl)-1,10-phenanthroline

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Technology Process of 2-(2',6'-difluorophenyl)-1,10-phenanthroline

There total 1 articles about 2-(2',6'-difluorophenyl)-1,10-phenanthroline which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 58.0%

: 13670-99-0
2,6-difluoroacetophenone

: 158753-17-4
8-amino-7-quinolinecarbaldehyde

: 1272029-49-8
2-(2',6'-difluorophenyl)-1,10-phenanthroline

Guidance literature:: With potassium hydroxide; In ethanol; for 15h; Inert atmosphere; Reflux;
DOI:10.1021/om101037k

Reference yield: 82.0%

: 1272029-49-8
2-(2',6'-difluorophenyl)-1,10-phenanthroline

: 3375-31-3
palladium diacetate

: (2-(2',6'-difluorophenyl)-1,10-phenanthroline)Pd(OAc)2*1/2CH₂Cl₂

Guidance literature:: In dichloromethane; toluene; soln. of Pd(OAc)2 in CH2Cl2 was added to stirred soln. of phenanthrolinein toluene, stirred for 24 h at room temp.; poured into petroleum ether, filtered, dried in vac., elem. anal.;
DOI:10.1021/om101037k

Reference yield: 19.0%

: 1272029-49-8
2-(2',6'-difluorophenyl)-1,10-phenanthroline

: 2923-28-6
silver trifluoromethanesulfonate

: 75-05-8,26809-02-9
acetonitrile

: palladium dichloride

: [(2-(2',6'-difluorophenyl)-1,10-phenanthroline)Pd(NCCH₃)2][OTf]2

Guidance literature:: In acetonitrile; byproducts: AgCl; (N2); PdCl2 and phenanthroline was refluxed in MeCN overnight, treated with AgOTf, refluxed in the dark for 2 d, AgOTf was added, refluxed in the dark for 1 d, evapd., dissolved in MeCN, filtered, AgOTf was added, refluxed for 4 d in the dark; evapd., MeCN was added, filtered through celite, Et2O was added, cooled to -25°C, crystd. overnight, filtered, dried in vac., elem. anal.;
DOI:10.1021/om101037k