Pt⁽²⁺⁾C₅H₄NC₅H₄N(CH₃)2SOC₆H₅^(1-)CF₃SO₃^(1-)=PtC₅H₄NC₅H₄N(CH₃)2SOC₆H₅CF₃SO₃

Base Information

Chemical Name:Pt⁽²⁺⁾*C₅H₄NC₅H₄N*(CH₃)2SO*C₆H₅^(1-)*CF₃SO₃^(1-)=PtC₅H₄NC₅H₄N(CH₃)2SOC₆H₅CF₃SO₃
CAS No.:308109-01-5
Molecular Formula:CF₃O₃S*C₂H₆OS*C₆H₅*C₁₀H₈N₂*Pt
Molecular Weight:655.578
Hs Code.:

Pt<sup>(2+)</sup>*C<sub>5</sub>H<sub>4</sub>NC<sub>5</sub>H<sub>4</sub>N*(CH<sub>3</sub>)2SO*C<sub>6</sub>H<sub>5</sub><sup>(1-)</sup>*CF<sub>3</sub>SO<sub>3</sub><sup>(1-)</sup>=PtC<sub>5</sub>H<sub>4</sub>NC<sub>5</sub>H<sub>4</sub>N(CH<sub>3</sub>)2SOC<sub>6</sub>H<sub>5</sub>CF<sub>3</sub>SO<sub>3</sub>

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Chemical Property of Pt⁽²⁺⁾*C₅H₄NC₅H₄N*(CH₃)2SO*C₆H₅^(1-)*CF₃SO₃^(1-)=PtC₅H₄NC₅H₄N(CH₃)2SOC₆H₅CF₃SO₃

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Technology Process of Pt⁽²⁺⁾*C₅H₄NC₅H₄N*(CH₃)2SO*C₆H₅^(1-)*CF₃SO₃^(1-)=PtC₅H₄NC₅H₄N(CH₃)2SOC₆H₅CF₃SO₃

There total 1 articles about Pt⁽²⁺⁾*C₅H₄NC₅H₄N*(CH₃)2SO*C₆H₅^(1-)*CF₃SO₃^(1-)=PtC₅H₄NC₅H₄N(CH₃)2SOC₆H₅CF₃SO₃ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

: 366-18-7
[2,2]bipyridinyl

: trans-Pt(DMSO)2ClPh

: 2923-28-6
silver trifluoromethanesulfonate

: 308109-01-5
Pt⁽²⁺⁾*C₅H₄NC₅H₄N*(CH₃)2SO*C₆H₅^(1-)*CF₃SO₃^(1-)=PtC₅H₄NC₅H₄N(CH₃)2SOC₆H₅CF₃SO₃

Guidance literature:: In dimethyl sulfoxide; byproducts: AgCl; AgCF3SO3 and Pt-complex were reacted in DMSO for a few h with stirring,filtered off, ligand was added under N2; filtered, solvent was evapd. under reduced pressure (0.1 mmHg, 70°C), washed with ether, recrystd. from CH2Cl2/ether;
DOI:10.1021/ic0004479

Reference yield:

: 308109-01-5
Pt⁽²⁺⁾*C₅H₄NC₅H₄N*(CH₃)2SO*C₆H₅^(1-)*CF₃SO₃^(1-)=PtC₅H₄NC₅H₄N(CH₃)2SOC₆H₅CF₃SO₃

: 603-35-0
triphenylphosphine

: PtC₅H₄NC₅H₄NP(C₆H₅)3C₆H₅⁽¹⁺⁾*CF₃SO₃^(1-)=PtC₅H₄NC₅H₄NC₆H₅P(C₆H₅)3CF₃SO₃

Guidance literature:: In further solvent(s); 1 eq. of Et2O added to a soln. of Zr complex at 25° in C6D5Br at25°; identified by NMR spectra;
DOI:10.1021/om000299u