cis-chloro-bis(triphenylphosphine)Pt(II) trichlorostannate(II)

Base Information

• Chemical Name: cis-chloro-bis(triphenylphosphine)Pt(II) trichlorostannate(II)
• CAS No.: 18583-19-2
• Molecular Formula: C₃₆H₃₀Cl₄P₂PtSn
• Molecular Weight: 980.184
• Mol file: 18583-19-2.mol

Synonyms:

Chemical Property of cis-chloro-bis(triphenylphosphine)Pt(II) trichlorostannate(II)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of cis-chloro-bis(triphenylphosphine)Pt(II) trichlorostannate(II)

There total 11 articles about cis-chloro-bis(triphenylphosphine)Pt(II) trichlorostannate(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 66.0%

cis-dichlorobis(triphenylphosphine)platinum(II) (10199-34-5,14056-88-3,15604-36-1) + tin(ll) chloride → cis-chloro-bis(triphenylphosphine)Pt(II) trichlorostannate(II) (32535-75-4,18583-19-2,18583-20-5)

Guidance literature:

In dichloromethane; stirred at room temp. for 2 h under N2; filtration, petroleum ether added, sepd., stand for 1 week at -20°C, pptd., elem. anal.;

Reference yield:

[Pt2Cl2(SnCl3)2(P(C6H5)3)2] (83719-67-9) → cis-dichlorobis(triphenylphosphine)platinum(II) (10199-34-5,14056-88-3,15604-36-1) + trans-(triphenylphosphine)3PtCl(1+) (47899-38-7) + cis-chloro-bis(triphenylphosphine)Pt(II) trichlorostannate(II) (32535-75-4,18583-19-2,18583-20-5)

Guidance literature:

With triphenylphosphine; In chloroform-d1; cold soln. of PPh3 in CDCl3 added dropwise to soln. of Pt complex in CDCl3 at 213 K; not isolated, monitored by NMR;

Reference yield:

trans-(triphenylphosphane)2PtH(SnCl3) (18117-31-2,82509-99-7,16902-94-6) → cis-chloro-bis(triphenylphosphine)Pt(II) trichlorostannate(II) (32535-75-4,18583-19-2,18583-20-5)

Guidance literature:

Multi-step reaction with 4 steps

1: dichloromethane

2: triphenyl phosphine; CO / ethanol

3: CHCl₃ / chloroform

4: HCl / dichloromethane

With triphenyl phosphine; CO; CHCl₃; HCl; In ethanol; dichloromethane; chloroform;

DOI:10.1021/om00058a019

upstream raw materials:

trans-{Pt(SnCl₃)(COC₅H₁₁)(PPh₃)2}

cis-dichlorobis(triphenylphosphine)platinum(II)

[Pt₂Cl₂(SnCl₃)2(P(C₆H₅)3)2]

trans-chlorohydridobis(triphenylphosphine)platinum(II)