[(C₅H₃N-1,3-(OP(i-Pr)2)2)Ru(H)(Cl)(triphenylphosphine)]

Base Information

Chemical Name:[(C₅H₃N-1,3-(OP(i-Pr)2)2)Ru(H)(Cl)(triphenylphosphine)]
CAS No.:1184293-76-2
Molecular Formula:C₃₅H₄₇ClNO₂P₃Ru
Molecular Weight:743.208
Hs Code.:

[(C<sub>5</sub>H<sub>3</sub>N-1,3-(OP(i-Pr)2)2)Ru(H)(Cl)(triphenylphosphine)]

Synonyms:

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Chemical Property of [(C₅H₃N-1,3-(OP(i-Pr)2)2)Ru(H)(Cl)(triphenylphosphine)]

Chemical Property:

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Technology Process of [(C₅H₃N-1,3-(OP(i-Pr)2)2)Ru(H)(Cl)(triphenylphosphine)]

There total 2 articles about [(C₅H₃N-1,3-(OP(i-Pr)2)2)Ru(H)(Cl)(triphenylphosphine)] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.3%

: 55102-19-7
hydridochlorotris(triphenylphosphine)ruthenium(II)

: 1184293-74-0
2,6-bis(diisopropylphosphinito)pyridine

: 1184293-76-2
[(C₅H₃N-1,3-(OP(i-Pr)2)2)Ru(H)(Cl)(triphenylphosphine)]

Guidance literature:: In benzene; byproducts: PPh3; (N2); using Schlenk techniques; addn. of soln. of C5H3N(OP(i-Pr)2)2 in benzene to benzene slurry of HRu(Cl)(PPh3)3; heating at 80°C for 30 min; removal of solvent under vac., dissolving in benzene, loading into silica gel column, eluting with pentane/benzene mixt. (1:1) for removal of PPh3, eluting with benzene and then with THF, removal of solvent under vac.;
DOI:10.1021/om9004077

Reference yield:

: 1184293-77-3
trans-[(C₅H₃N-1,3-(OP(i-Pr)2)2)Ru(H)2(triphenylphosphine)]

: 98-88-4
benzoyl chloride

: 1184293-76-2
[(C₅H₃N-1,3-(OP(i-Pr)2)2)Ru(H)(Cl)(triphenylphosphine)]

Guidance literature:: In benzene-d6; byproducts: benzaldehyde; (N2); using Schlenk techniques; addn. of 1 equiv. of PhCOCl to C6D6 soln. of (C5H3N(OP(i-Pr)2)2)Ru(H)2(PPh3) in a septum-capped NMR tube, heating at 80°C for 5 h; monitoring by NMR;
DOI:10.1021/om9004077

Reference yield: 99.6%

: 1184293-76-2
[(C₅H₃N-1,3-(OP(i-Pr)2)2)Ru(H)(Cl)(triphenylphosphine)]

: sodium triethylborohydride

: 1184293-77-3
trans-[(C₅H₃N-1,3-(OP(i-Pr)2)2)Ru(H)2(triphenylphosphine)]

Guidance literature:: In tetrahydrofuran; toluene; (N2); using Schlenk techniques; addn. of 1 equiv. of NaHBEt3 in toluene to a cooled (-35°C) THF soln. of Ru(H)Cl(PPh3)(C5H3N(OP(i-Pr)2)2); keeping at -35°C for 1 h, warming to room temp., stirring for 1h; filtration through cotton/Celite pad, removal of solvent from filtrate under vac., elem. anal.;
DOI:10.1021/om9004077