(-)-β-(epi)-necrodol

Base Information

Chemical Name:(-)-β-(epi)-necrodol
CAS No.:104113-51-1
Molecular Formula:C₁₀H₁₈O
Molecular Weight:154.252
Hs Code.:

Synonyms:

Suppliers and Price of (-)-β-(epi)-necrodol

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (-)-β-(epi)-necrodol

Chemical Property:

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Technology Process of (-)-β-(epi)-necrodol

There total 11 articles about (-)-β-(epi)-necrodol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 97.0%

: 2,2,3-trimethyl-4-methylenecyclopentanecarboxylic acid ethyl ester

: 104086-70-6,104113-51-1,120664-44-0,125276-85-9,125276-88-2
β-necrodol

Guidance literature:: With lithium aluminium tetrahydride; In diethyl ether; at 20 ℃; for 1h;
DOI:10.1021/jf904452v

Reference yield:

: 70908-42-8
α,α-dimethyl allyl methyl carbonate

: 104086-70-6,104113-51-1,120664-44-0,125276-85-9,125276-88-2
β-necrodol

Guidance literature:: Multi-step reaction with 5 steps

1: BSA / Mo(CO)6 / toluene / 100 °C

2: 60 percent / NaCN / dimethylsulfoxide; H₂O / 160 °C

3: 66 percent / LDA / tetrahydrofuran / -78 °C

4: trimethylsilane / (dba)3Pd_2.CHCl₃, (o-C₇H₇)3P, acetic acid / benzene

5: LAH

With benzenesulfonamide; lithium aluminium tetrahydride; trimethylsilan; sodium cyanide; lithium diisopropyl amide; tris(dibenzylideneacetone)dipalladium⁽⁰⁾ chloroform complex; hexacarbonyl molybdenum; acetic acid; tris-(o-tolyl)phosphine; In tetrahydrofuran; water; dimethyl sulfoxide; toluene; benzene;
DOI:10.1016/S0040-4039(00)80263-4

Reference yield:

: 74866-35-6
2-(1,1-dimethylallyl)malonic acid dimethyl ester

: 104086-70-6,104113-51-1,120664-44-0,125276-85-9,125276-88-2
β-necrodol

Guidance literature:: Multi-step reaction with 4 steps

1: 60 percent / NaCN / dimethylsulfoxide; H₂O / 160 °C

2: 66 percent / LDA / tetrahydrofuran / -78 °C

3: trimethylsilane / (dba)3Pd_2.CHCl₃, (o-C₇H₇)3P, acetic acid / benzene

4: LAH

With lithium aluminium tetrahydride; trimethylsilan; sodium cyanide; lithium diisopropyl amide; tris(dibenzylideneacetone)dipalladium⁽⁰⁾ chloroform complex; acetic acid; tris-(o-tolyl)phosphine; In tetrahydrofuran; water; dimethyl sulfoxide; benzene;
DOI:10.1016/S0040-4039(00)80263-4