[2-amino-5,10,15,20-tetrakis(3',5'-di-tert-butylphenyl)porphyrinato]copper(II)

Base Information

Chemical Name:[2-amino-5,10,15,20-tetrakis(3',5'-di-tert-butylphenyl)porphyrinato]copper(II)
CAS No.:185447-16-9
Molecular Formula:C₇₆H₉₃CuN₅
Molecular Weight:1140.15
Hs Code.:

Synonyms:

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of [2-amino-5,10,15,20-tetrakis(3',5'-di-tert-butylphenyl)porphyrinato]copper(II)

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Technology Process of [2-amino-5,10,15,20-tetrakis(3',5'-di-tert-butylphenyl)porphyrinato]copper(II)

There total 1 articles about [2-amino-5,10,15,20-tetrakis(3',5'-di-tert-butylphenyl)porphyrinato]copper(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 89.0%

: 16940-66-2
sodium tetrahydroborate

: 185447-13-6
[2-nitro-5,10,15,20-tetrakis(3',5'-di-tert-butylphenyl)porphyrinato]copper(II)

: 185447-16-9
[2-amino-5,10,15,20-tetrakis(3',5'-di-tert-butylphenyl)porphyrinato]copper(II)

Guidance literature:: With 10percent palladium on activated carbon; In methanol; dichloromethane; addn. of 10% Pd-C to a soln. of copper complex in CH2Cl2-methanol mixt. (4:1), degassing with N2, addn. of NaBH4 in small portions over 6 min, stirring at room temp. in the dark under N2 for 1 h; evapn., passing through a plug of silica (CH2Cl2), evapn., column chromy(SiO2, CH2Cl2/light petroleum 1:4, darkness), evapn., recrystn.(CH2Cl2/ methanol);
DOI:10.1039/b007389j

Reference yield: 37.0%

: 185447-16-9
[2-amino-5,10,15,20-tetrakis(3',5'-di-tert-butylphenyl)porphyrinato]copper(II)

: 214962-07-9
[2,3-dioxo-5,10,15,20-tetrakis(3',5'-di-tert-butylphenyl)chlorinato]copper(II)

Guidance literature:: With Dess-Martin periodane; In dichloromethane; addn. of Dess-Martin periodinane to a soln. of copper complex in CH2Cl2,stirring at room temp. in the dark for 5 h, addn. of Dess-Martin period inane, stirring for 11 h; addn. of 1M HCl, stirring for 45 min, washing org. layer with water, 5% NaHCO3, water, drying (Na2SO4), filtration, evapn., column chromy (SiO2,CH2Cl2/light petroleum 2:3-1:1);
DOI:10.1039/b007389j