BrMn(CO)3((o-CH₃C₆H₄O)3P)2

Base Information

Chemical Name:BrMn(CO)3((o-CH₃C₆H₄O)3P)2
CAS No.:90423-24-8
Molecular Formula:C₄₅H₄₂BrMnO₉P₂
Molecular Weight:923.613
Hs Code.:

BrMn(CO)3((o-CH<sub>3</sub>C<sub>6</sub>H<sub>4</sub>O)3P)2

Synonyms:

Suppliers and Price of BrMn(CO)3((o-CH₃C₆H₄O)3P)2

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of BrMn(CO)3((o-CH₃C₆H₄O)3P)2

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of BrMn(CO)3((o-CH₃C₆H₄O)3P)2

There total 2 articles about BrMn(CO)3((o-CH₃C₆H₄O)3P)2 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

: 14516-54-2
bromopentacarbonylmanganese(I)

: 2622-08-4
tri(O-methylphenyl)phosphite

: 113626-72-5,90423-24-8
bromotricarbonylbis(tri-ortho-tolylphosphite)manganese

Guidance literature:: In acetone; refluxing under inert gas, 4 h; cooling, filtration; elem. anal.;

Reference yield: 53.0%

: 14516-54-2
bromopentacarbonylmanganese(I)

: 2622-08-4
tri(O-methylphenyl)phosphite

: 90423-24-8,113626-72-5
BrMn(CO)3((o-CH₃C₆H₄O)3P)2

Guidance literature:: In chloroform; BrMn(CO)5 and (o-CH3C6H4)3P dissolved in CHCl3, stirred at 55°C for 18 h; solvent vac.-stripped, hexane added;
DOI:10.1246/bcsj.60.2280

Reference yield: 80.0%

: 113626-72-5,90423-24-8
bromotricarbonylbis(tri-ortho-tolylphosphite)manganese

: 84180-15-4,90458-73-4
hydridotricarbonylbis(tri-ortho-tolylphosphite)manganese

Guidance literature:: With sodium amalgam; acetic acid; In tetrahydrofuran; byproducts: NaBr, CH3CO2Na; shaking Mn complex with sodium amalgam (excess) under N2, 2 h; separating Hg; addn. of equimolar amt. of acetic acid, -80°C; warm up to room temp., filtn., removal of solvent, chromy. (silica gel, petroleum ether/ether); elem. anal.;