(dl)-3-methyl-1-phenylheptane

Base Information

• Chemical Name: (dl)-3-methyl-1-phenylheptane
• CAS No.: 102614-92-6
• Molecular Formula: C₁₄H₂₂
• Molecular Weight: 190.329
• Mol file: 102614-92-6.mol

Synonyms:

Chemical Property of (dl)-3-methyl-1-phenylheptane

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (dl)-3-methyl-1-phenylheptane

There total 10 articles about (dl)-3-methyl-1-phenylheptane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 82.0%

(rac)-(3-iodobutyl)benzeze (59456-20-1) + butyl magnesium bromide (693-04-9) → (dl)-3-methyl-1-phenylheptane (102614-92-6,102680-23-9,90753-42-7)

Guidance literature:

With copper(l) iodide; buta-1,3-diene; In tetrahydrofuran; at -78 - 0 ℃;

DOI:10.1039/c2cc34847k

Reference yield: 80.0%

C20H25ClS → (dl)-3-methyl-1-phenylheptane (102614-92-6,102680-23-9,90753-42-7)

Guidance literature:

With triethylsilane; tris(pentafluorophenyl)borate; In chloroform-d1; at 20 ℃; for 90h; chemoselective reaction;

DOI:10.1021/acs.orglett.5b01651

Reference yield:

(rac)-(3-iodobutyl)benzeze (59456-20-1) + butyl magnesium bromide (693-04-9) → 4-Phenylbut-1-ene (768-56-9) + 1-butylbenzene (104-51-8) + 1-phenyl-2-butene (1560-06-1) + (dl)-3-methyl-1-phenylheptane (102614-92-6,102680-23-9,90753-42-7)

Guidance literature:

With copper(l) iodide; In tetrahydrofuran; at -78 - 0 ℃;

DOI:10.1039/c2cc34847k

upstream raw materials:

styrene

di-n-hexylmagnesium

phenethylmagnesium bromide

n-hexan-2-one

Refernces

• 1、 Di Franco, Thomas,Stojanovic, Marko,Keller, Sébastien Carlos,Scopelliti, Rosario,Hu, Xile. "A Structure–Activity Study of Nickel NNN Pincer Complexes for Alkyl-Alkyl Kumada and Suzuki–Miyaura Coupling Reactions". . p. 830 - 847. Retrieved 2016/11/11.
• 2、 Shen, Ruwei,Iwasaki, Takanori,Terao, Jun,Kambe, Nobuaki. "Copper-catalyzed coupling reaction of unactivated secondary alkyl iodides with alkyl Grignard reagents in the presence of 1,3-butadiene as an effective additive". supporting information; scheme or table. p. 9313 - 9315. Retrieved 2012/09/21.