1560-06-1

Basic information

• Product Name: 1-PHENYL-2-BUTENE
• Synonyms: 1-PHENYL-2-BUTENE;(2E)-2-Butenylbenzene;1-phenyl-2-buten;1-Phenylbutene-2;2-Butene, 1-phenyl-;2-butenyl-benzen;2-butenylbenzene;4-Phenyl-2-butene
• CAS NO: 1560-06-1
• Molecular Formula: C₁₀H₁₂
• Molecular Weight: 132.2
• EINECS: 216-328-4
• Mol File: 1560-06-1.mol
• Article Data: 58

Chemical Properties

• Melting Point: -41.43°C (estimate)
• Boiling Point: 176.05°C
• Flash Point: 56.2°C
• Appearance: /
• Density: 0.8831
• Vapor Pressure: 1.5mmHg at 25°C
• Refractive Index: 1.5101
• CAS DataBase Reference: 1-PHENYL-2-BUTENE(CAS DataBase Reference)
• NIST Chemistry Reference: 1-PHENYL-2-BUTENE(1560-06-1)
• EPA Substance Registry System: 1-PHENYL-2-BUTENE(1560-06-1)

Safety Data

• Hazardous Substances Data: 1560-06-1(Hazardous Substances Data)

Usage

Synthesis Reference(s)

The Journal of Organic Chemistry, 49, p. 4309, 1984 DOI: 10.1021/jo00196a043Tetrahedron Letters, 25, p. 3207, 1984 DOI: 10.1016/S0040-4039(01)91010-X

InChI:InChI=1/C10H12/c1-2-3-7-10-8-5-4-6-9-10/h2-6,8-9H,7H2,1H3/b3-2+

Upstream product

• 60-29-7 diethyl ether 
• 408335-61-5 1-but-2ξ-enyloxy-2-methoxy-benzene 
• 67-56-1 methanol 
• 64283-87-0 4-phenyl-1-iodobutane 
• 13633-25-5 1-Bromo-4-phenylbutane 
• 4784-77-4 (E/Z)-crotyl bromide 
• 16635-23-7 phenyltriisopropoxytitanium(IV) 
• 95576-66-2 phenyltriethoxytitanium 
• 25483-62-9 (N(C₂H₅)2)3Ti(C₆H₅) 
• 108968-42-9 Ti(OC(CH₃)3)3(C₆H₅) 
• 108968-43-0 Ti(OC₆H₅)3(C₆H₅) 
• 65512-08-5 4-phenylbutyl methanesulfonate 
• 32644-22-7 1-methyl-3-phenylallene 
• 16215-13-7 trans-Cinnamyl-(4-chlor-phenyl)-sulfon 

Downstream Products

• 825-55-8 2-phenylthiophene 
• 20849-77-8 3-chloro-4-phenylbutan-2-one 
• 24767-67-7 3-chloro-1-phenyl-2-butanone 
• 824-90-8 1-phenylbut-1-ene 
• 39830-31-4 2-benzyl-3-methyloxirane 
• 767-58-8 1-methylindane 
• 122-78-1 phenylacetaldehyde 
• 2344-70-9 1-phenyl-3-butanol 
• 1392095-68-9 (E)-1-methoxy-4-(3-phenylhex-1-en-1-yl)benzene 
• 100-52-7 benzaldehyde 
• 1450899-55-4 (5R,6R)-5-benzyl-2,2,3,3,6,8,8,9,9-nonamethyl-4,7-dioxa-3,8-disiladecane 
• 139165-56-3 threo-(2R,3R)-1-phenyl-2,3-butanediol 
• 143097-80-7 2-bromo-4-phenylbutane 

Relevant articles and documents

-

-

-

-

CROSS COUPLING OF PHENYLMANGANESE IODIDE WITH ALLYL AND PROPARGYL ACETATES

-

One-Pot Deoxygenation and Substitution of Alcohols Mediated by Sulfuryl Fluoride

Sulfuryl fluoride is a valuable reagent for the one-pot activation and derivatization of aliphatic alcohols, but the highly reactive alkyl fluorosulfate intermediates limit both the types of reactions that can be accessed as well as the scope. Herein, we report the SO2F2-mediated alcohol substitution and deoxygenation method that relies on the conversion of fluorosulfates to alkyl halide intermediates. This strategy allows the expansion of SO2F2-mediated one-pot processes to include radical reactions, where the alkyl halides can also be exploited in the one-pot deoxygenation of primary alcohols under mild conditions (52-95% yield). This strategy can also enhance the scope of substitutions to nucleophiles that are previously incompatible with one-pot SO2F2-mediated alcohol activation and enables substitution of primary and secondary alcohols in 54-95% yield. Chiral secondary alcohols undergo a highly stereospecific (90-98% ee) double nucleophilic displacement with an overall retention of configuration.

Reduction of α,β-unsaturated carbonyl compounds and 1,3-diketones in aqueous media, using a raney ni-al alloy

The treatment of α,β-unsaturated carbonyl compounds and 1,3-diketones with Raney Ni-Al alloy in aqueous media yielded as major reaction products the corresponding saturated alcohols and/or the corresponding hydrocarbons, in a complete transformation of the starting material.

Reduction of α,β-Unsaturated carbonyl compounds and 1,3-Diketones in aqueous media, using a raney ni-al alloy

The treatment of α,β-unsaturated carbonyl compounds and 1,3-diketones with Raney Ni-Al alloy in aqueous media yielded as major reaction products the corresponding saturated alcohols and/or the corresponding hydrocarbons, in a complete transformation of the starting material.