[PtPh(5-Mes₂B-2-Ph-pyridine(-H))(dimethylsulfoxide)]

Base Information

• Chemical Name: [PtPh(5-Mes₂B-2-Ph-pyridine(-H))(dimethylsulfoxide)]
• CAS No.: 1181650-71-4
• Molecular Formula: C₃₇H₄₀BNOPtS
• Molecular Weight: 752.688
• Mol file: 1181650-71-4.mol

Synonyms:

Chemical Property of [PtPh(5-Mes₂B-2-Ph-pyridine(-H))(dimethylsulfoxide)]

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [PtPh(5-Mes₂B-2-Ph-pyridine(-H))(dimethylsulfoxide)]

There total 1 articles about [PtPh(5-Mes₂B-2-Ph-pyridine(-H))(dimethylsulfoxide)] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 60.0%

bis(dimethylsulfoxide)diphenylplatinum(II) + 5-(dimesitylboranyl)-2-phenylpyridine (1181650-67-8) → [PtPh(5-Mes2B-2-Ph-pyridine(-H))(dimethylsulfoxide)] (1181650-71-4)

Guidance literature:

In tetrahydrofuran; (N2, Schlenk technique); addn. of pyridine deriv. to THF soln. of platinum compd., stirring at 50°C for 6 h; evapn., recrystn. (hexane/CH2Cl2), drying in vac., elem. anal.;

DOI:10.1021/ic9007069

Reference yield: 85.0%

4,4'-bipyridine (553-26-4) + dichloromethane (75-09-2) + [PtPh(5-Mes2B-2-Ph-pyridine(-H))(dimethylsulfoxide)] (1181650-71-4) → [(PtPh(5-Mes2B-2-Ph-pyridine(-H)))2(4,4'-bipyridine)]*0.33CH2Cl2

Guidance literature:

In dichloromethane; (N2, Schlenk technique); addn. of bipyridine in CH2Cl2 to CH2Cl2 soln. of platinum compd.; layering with hexane, keeping at room temp. overnight, isolation of crystals, elem. anal.;

DOI:10.1021/ic9007069

Reference yield: 70.0%

[PtPh(5-Mes2B-2-Ph-pyridine(-H))(dimethylsulfoxide)] (1181650-71-4) + water (7732-18-5) → [PtPh(5-Mes(HO)B-2-Ph-pyridine(-H))(dimethylsulfoxide)] (1181650-73-6)

Guidance literature:

In tetrahydrofuran; toluene; byproducts: mesitylene; addn. of toluene to THF soln. of platinum compd., keeping in air at roomtemp. with slow evapn. for 20 d; isolation of crystals, elem. anal.;

DOI:10.1021/ic9007069

upstream raw materials:

5-(dimesitylboranyl)-2-phenylpyridine

Downstream raw materials:

[PtPh(5-Mes(HO)B-2-Ph-pyridine(-H))(dimethylsulfoxide)]