fac-[Rh(κ3-P,O,P-Xantphos)(P(cyclopentyl)2(η2-C5H7))][B(C6H3-3,5-(CF3)2)4]

Base Information

Chemical Name:fac-[Rh(κ3-P,O,P-Xantphos)(P(cyclopentyl)2(η2-C5H7))][B(C6H3-3,5-(CF3)2)4]
CAS No.:1354037-32-3
Molecular Formula:C₃₂H₁₂BF₂₄*C₅₄H₅₇OP₃Rh
Molecular Weight:1781.09
Hs Code.:

Synonyms:

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Chemical Property of fac-[Rh(κ3-P,O,P-Xantphos)(P(cyclopentyl)2(η2-C5H7))][B(C6H3-3,5-(CF3)2)4]

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Technology Process of fac-[Rh(κ3-P,O,P-Xantphos)(P(cyclopentyl)2(η2-C5H7))][B(C6H3-3,5-(CF3)2)4]

There total 1 articles about fac-[Rh(κ3-P,O,P-Xantphos)(P(cyclopentyl)2(η2-C5H7))][B(C6H3-3,5-(CF3)2)4] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 74.0%

: 1033128-87-8
[Rh(η6-C6H5F)(P(cyclopentyl)2(η2-C5H7))][B(C6H3-3,5-(CF3)2)4]

: 161265-03-8
4,5-bis(diphenylphosphino)-9,9-dimethylxanthene

: 1354037-32-3
fac-[Rh(κ3-P,O,P-Xantphos)(P(cyclopentyl)2(η2-C5H7))][B(C6H3-3,5-(CF3)2)4]

Guidance literature:: In dichloromethane; byproducts: C6H5F; (Ar); using Schlenk techniques; addn. of Xantphos to soln. of Rh(η6-C6H5F)(PCyp2(η5-C5H7))(B(C6H3(CF3)2)4) in CH2Cl2, stirring for 2 h; removal of solvent in vac., washing with pentane, drying under reduced pressure, diffusion of pentane into soln. in C6H5F, crystn.; elem. anal.;
DOI:10.1021/om201034m

Reference yield:

: 1354037-32-3
fac-[Rh(κ3-P,O,P-Xantphos)(P(cyclopentyl)2(η2-C5H7))][B(C6H3-3,5-(CF3)2)4]

: 1333-74-0
hydrogen

: 1354037-52-7
[Rh(κ3-P,O,P-Xantphos)(tricyclopentylphosphine)][B(C6H3-3,5-(CF3)2)4]

Guidance literature:: In fluorobenzene; (Ar); using Schlenk techniques; placing of fluorobenzene soln. of (Rh(O(C6H3PPh2)2CMe2)(P(C5H9)2C5H7))(B(C6H3(CF3)2)4) under 4 atm of H2, shaking, standing for 5 ds, removal of H2 under vac. by freeze/pump/thaw of the soln.; removal of solvent under reduced pressure, washing with pentane, drying in vac.;
DOI:10.1021/om201034m

Reference yield:

: 1354037-32-3
fac-[Rh(κ3-P,O,P-Xantphos)(P(cyclopentyl)2(η2-C5H7))][B(C6H3-3,5-(CF3)2)4]

: 1333-74-0
hydrogen

: 1354729-75-1
mer-[RhH2(κ3-P,O,P-Xantphos)(tricyclopentylphosphine)][B(C6H3-3,5-(CF3)2)4]

: fac-[RhH2(κ3-P,O,P-Xantphos)(tricyclopentylphosphine)][B(C6H3-3,5-(CF3)2)4]

Guidance literature:: In dichloromethane-d2; (Ar); using Schlenk techniques; freezing of CD2Cl2 soln. of (Rh(O(C6H3PPh2)2CMe2)(P(C5H9)2C5H7))(B(C6H3(CF3)2)4) in liq. N2, placing under vac.,filling with H2, shaking for 10 min, standing for 5 ds; monitoring by NMR;
DOI:10.1021/om201034m