5,17-bis(zinc(II)(2,8,12,18-tetramethyl-3,7,13,17-tetraethyl-10-phenylphorphyrinate)-25,27-dimethoxy-26,28-dihydroxycalix-[4]-arene)

Base Information

Chemical Name:5,17-bis(zinc(II)(2,8,12,18-tetramethyl-3,7,13,17-tetraethyl-10-phenylphorphyrinate)-25,27-dimethoxy-26,28-dihydroxycalix-[4]-arene)
CAS No.:1106732-15-3
Molecular Formula:C₁₀₆H₁₀₄N₈O₄Zn₂
Molecular Weight:1684.82
Hs Code.:

5,17-bis(zinc(II)(2,8,12,18-tetramethyl-3,7,13,17-tetraethyl-10-phenylphorphyrinate)-25,27-dimethoxy-26,28-dihydroxycalix-[4]-arene)

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Chemical Property of 5,17-bis(zinc(II)(2,8,12,18-tetramethyl-3,7,13,17-tetraethyl-10-phenylphorphyrinate)-25,27-dimethoxy-26,28-dihydroxycalix-[4]-arene)

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Technology Process of 5,17-bis(zinc(II)(2,8,12,18-tetramethyl-3,7,13,17-tetraethyl-10-phenylphorphyrinate)-25,27-dimethoxy-26,28-dihydroxycalix-[4]-arene)

There total 1 articles about 5,17-bis(zinc(II)(2,8,12,18-tetramethyl-3,7,13,17-tetraethyl-10-phenylphorphyrinate)-25,27-dimethoxy-26,28-dihydroxycalix-[4]-arene) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 6.0%

: 92415-30-0
bis(3-ethyl-4-methyl-1H-pyrrol-2-yl)methane

: 557-34-6
zinc diacetate

: 125065-68-1,129645-60-9
26,28-Dihydroxy-25,27-dimethoxypentacyclo<19.3.1.1^3,7.1^9,13.1^15,19>octacosa-1(25),3,5,7(28),9,11,13(27),15,17,19(26),21,23-dodecaene-5,17-dicarboxaldehyde

: 100-52-7
benzaldehyde

: 1106732-15-3
5,17-bis(zinc(II)(2,8,12,18-tetramethyl-3,7,13,17-tetraethyl-10-phenylphorphyrinate)-25,27-dimethoxy-26,28-dihydroxycalix-[4]-arene)

Guidance literature:: With trichloroacetic acid; In dichloromethane; acetonitrile; CCl3COOH in MeCN added to calixarene, amine, and aldehyde (1:4:2 mol) inMeCN/CH2Cl2, stirred (Ar, 3 h); quinone in CH2Cl2 added, stirred (2 h), concd., washed (aq. NH3), ppt. dried, CH2Cl2 added, satd. soln. of Zn s alt in MeOH added, stirred (0.5 h); filtered, filtrate concd.; chromy. (Al2O3, CH2Cl2/C6H14 1:2); elem. anal.;
DOI:10.1134/S1070328407100119

Reference yield: 87.0%

: 1106732-15-3
5,17-bis(zinc(II)(2,8,12,18-tetramethyl-3,7,13,17-tetraethyl-10-phenylphorphyrinate)-25,27-dimethoxy-26,28-dihydroxycalix-[4]-arene)

: 41024-91-3
penta(ethylene glycol) bis(p-toluenesulfonate)

: 1106732-19-7
5,17-bis(zinc(II)(2,8,12,18-tetramethyl-3,7,13,17-tetraethyl-10-phenylphorphyrinate)-25,27-dimethoxy-26,28-crown-[6]-calix-[4]-arene)

Guidance literature:: With caesium carbonate; In N,N-dimethyl-formamide; acetonitrile; under Ar; Cs2CO3 and pentaethylene glycol di(p-toluenesulfonate) added to soln. of Zn complex in DMF/MeCN (1:2), mixt. heated with stirring for 24 h; evapd. under vac., residue extd. with CH2Cl3/aq. HCl, org. layer sepd., washed with H2O, dried over Na2SO4, filtrate evapd., chromy. (Al2O3, CH2Cl2/C6H14 1:1 or 1:2), evapd. under vac., recrystd. from CH2Cl2/CH3OH (1:1); elem. anal.;
DOI:10.1134/S1070328407100119

Reference yield:

: 1106732-15-3
5,17-bis(zinc(II)(2,8,12,18-tetramethyl-3,7,13,17-tetraethyl-10-phenylphorphyrinate)-25,27-dimethoxy-26,28-dihydroxycalix-[4]-arene)

: 107-15-3,85404-18-8
ethylenediamine

: 5,17-bis(zinc(II)(2,8,12,18-tetramethyl-3,7,13,17-tetraethyl-10-phenylphorphyrinate)-25,27-dimethoxy-26,28-dihydroxycalix-[4]-arene)-bis(1,2-diaminoethane)

Guidance literature:: In toluene; at 298 K in toluene at molar ratio of 1:2 of Zn complex:NH2C2H4NH2; not isolated detd. by UV-vis spectroscopy;
DOI:10.1134/S1070328408060067