Technology Process of anti-(2S,3S,5S)-2,3-epoxy-3-methyl-5-phenylcyclohexanone
There total 2 articles about anti-(2S,3S,5S)-2,3-epoxy-3-methyl-5-phenylcyclohexanone which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
With
9-amino(9-deoxy)epiquinidine di(trifluoroacetic acid); dihydrogen peroxide;
In
1,4-dioxane; water;
at 50 ℃;
for 48h;
enantioselective reaction;
DOI:10.1021/ja402058v
- Guidance literature:
-
Multi-step reaction with 2 steps
1: 9-epi-9-amino-9-deoxyquinine; acetic acid / toluene / 48 h / -15 °C
2: dihydrogen peroxide; 9-amino(9-deoxy)epiquinidine di(trifluoroacetic acid) / water; 1,4-dioxane / 48 h / 50 °C
With
9-epi-9-amino-9-deoxyquinine; 9-amino(9-deoxy)epiquinidine di(trifluoroacetic acid); dihydrogen peroxide; acetic acid;
In
1,4-dioxane; water; toluene;
DOI:10.1021/ja402058v
