RuH(C₆H₅NC(CH₃)NC₆H₅)(CO)(P(C₆H₅)3)2

Base Information

Chemical Name:RuH(C₆H₅NC(CH₃)NC₆H₅)(CO)(P(C₆H₅)3)2
CAS No.:142496-52-4
Molecular Formula:C₅₁H₄₄N₂OP₂Ru
Molecular Weight:863.941
Hs Code.:

RuH(C<sub>6</sub>H<sub>5</sub>NC(CH<sub>3</sub>)NC<sub>6</sub>H<sub>5</sub>)(CO)(P(C<sub>6</sub>H<sub>5</sub>)3)2

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Suppliers and Price of RuH(C₆H₅NC(CH₃)NC₆H₅)(CO)(P(C₆H₅)3)2

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of RuH(C₆H₅NC(CH₃)NC₆H₅)(CO)(P(C₆H₅)3)2

Chemical Property:

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Technology Process of RuH(C₆H₅NC(CH₃)NC₆H₅)(CO)(P(C₆H₅)3)2

There total 7 articles about RuH(C₆H₅NC(CH₃)NC₆H₅)(CO)(P(C₆H₅)3)2 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 93.0%

: 15529-49-4,41756-81-4
tris(triphenylphosphine)ruthenium(II) chloride

: 621-09-0,141417-91-6,1086215-03-3,1452517-10-0
N,N'-diphenylacetamidine

: 142496-52-4
carbonyl(N,N'-diphenylacetamidinato)hydridobis(triphenylphosphine)ruthenium(II)

Guidance literature:: With triethylamine; In ethanol; under N2: heating of (RuCl2(P(C6H5)3)3), amidine and triethylamine in ethanol under reflux for 4 h; addn. of further triethylamine at hourly intervals; cooling; filtration;; concn. under reduced pressure; filtration; washing with methanol, water, methanol and light petroleum; drying in vac.; elem. anal.;
DOI:10.1039/DT9930002827

Reference yield: 77.0%

: 157072-60-1,61521-25-3,166941-05-5,16971-33-8
(carbonyl)(chloro)(hydrido)tris(triphenylphosphine)ruthenium(II)

: 621-09-0,141417-91-6,1086215-03-3,1452517-10-0
N,N'-diphenylacetamidine

: 142496-52-4
carbonyl(N,N'-diphenylacetamidinato)hydridobis(triphenylphosphine)ruthenium(II)

Guidance literature:: With triethylamine; In ethanol; benzene; under N2: addn. of amidine in ethanol and triethylamine to (RuH(Cl)(CO)(P(C6H5)3)3) in benzene; heating under reflux for 2 h; cooling; filtration;; dilution with methanol; storing overnight at 5°C; filtration of crystals; washing (methanol, water, methanol, light petroleum); drying in vac.; elem. anal.;
DOI:10.1039/DT9930002827

Reference yield: 75.0%

: 25360-32-1,22337-78-6
carbonyl bis(hydrido)tris(triphenylphosphine)ruthenium(II)

: 621-09-0,141417-91-6,1086215-03-3,1452517-10-0
N,N'-diphenylacetamidine

: 142496-52-4
carbonyl(N,N'-diphenylacetamidinato)hydridobis(triphenylphosphine)ruthenium(II)

Guidance literature:: In toluene; under N2: addn. of (RuH2(CO)(P(C6H5)3)3) to a stirred soln. of amidine in toluene; heating under reflux for 6 h; cooling; filtration;; dilution with methanol; cooling; filtration; washing (methanol and light petroleum); drying in vac.; elem. anal.;
DOI:10.1039/DT9930002827