cis-oxo(p-tolylimido)bis(diethyldithiocarbamato)molybdenum(VI)

Base Information

• Chemical Name: cis-oxo(p-tolylimido)bis(diethyldithiocarbamato)molybdenum(VI)
• CAS No.: 75900-17-3
• Molecular Formula: C₁₇H₂₇MoN₃OS₄
• Molecular Weight: 513.625
• Mol file: 75900-17-3.mol

Synonyms:

Chemical Property of cis-oxo(p-tolylimido)bis(diethyldithiocarbamato)molybdenum(VI)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of cis-oxo(p-tolylimido)bis(diethyldithiocarbamato)molybdenum(VI)

There total 1 articles about cis-oxo(p-tolylimido)bis(diethyldithiocarbamato)molybdenum(VI) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

bis(diethylcarbamodithioato-S,S')oxomolybdenum (63950-40-3,25395-92-0) + p-methylazidobenzene (2101-86-2) → cis-oxo(p-tolylimido)bis(diethyldithiocarbamato)molybdenum(VI) (75900-17-3)

Guidance literature:

In dichloromethane; (either in vac. or under N2); to the starting complex addn. of tolyl azide in CH2Cl2 (1 h, room temp.); filtration, trituration with hexane, dried in vac., elem. anal.;

Reference yield:

cis-oxo(p-tolylimido)bis(diethyldithiocarbamato)molybdenum(VI) (75900-17-3) → {Mo(NC6H4(CH3))(S2CN(C2H5)2)2}2O*CH2Cl2

Guidance literature:

With triphenylphosphine; In dichloromethane; byproducts: (C6H5)3PO; (either in vac. or under N2); to the starting complex addn. of triphenyl phosphine in CH2Cl2 (12 h, room temp.); trituration with ether, filtration, dried in vac., elem. anal.;

Reference yield:

cis-oxo(p-tolylimido)bis(diethyldithiocarbamato)molybdenum(VI) (75900-17-3) + dimethyl acetylenedicarboxylate (762-42-5) → Mo(NC6H4CH3)((CCO2CH3)2)(S2CN(C2H5)2)2

Guidance literature:

With P(C₆H₅)2(C₂H₅); In toluene; byproducts: (C2H5)(C6H5)2PO; (N2); to the starting complex and EtPh2P (in toluene, 55°C, 1 h) addn. of the dicarboxylate (at 55°C, 15 h); filtration, trituration with ether, washed with acetone, recrystn. with acetone, dried in vac., elem. anal.;

upstream raw materials:

bis(diethylcarbamodithioato-S,S')oxomolybdenum

p-methylazidobenzene