[RuCl(indenyl)(PPh₃)P(OC₁₀H₆)2N(CH₂Ph)2]

Base Information

Chemical Name:[RuCl(indenyl)(PPh₃)P(OC₁₀H₆)2N(CH₂Ph)2]
CAS No.:1190481-97-0
Molecular Formula:C₆₁H₄₈ClNO₂P₂Ru
Molecular Weight:1025.53
Hs Code.:

[RuCl(indenyl)(PPh<sub>3</sub>)P(OC<sub>10</sub>H<sub>6</sub>)2N(CH<sub>2</sub>Ph)2]

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Chemical Property of [RuCl(indenyl)(PPh₃)P(OC₁₀H₆)2N(CH₂Ph)2]

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Technology Process of [RuCl(indenyl)(PPh₃)P(OC₁₀H₆)2N(CH₂Ph)2]

There total 1 articles about [RuCl(indenyl)(PPh₃)P(OC₁₀H₆)2N(CH₂Ph)2] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 87.0%

: (R)-binol-N,N-dibenzylphosphoramidite

: (η5-indenyl)ruthenium(bis(triphenylphosphine))chloride

: 1190481-97-0
[RuCl(indenyl)(PPh₃)P(OC₁₀H₆)2N(CH₂Ph)2]

Guidance literature:: In tetrahydrofuran; THF added to Schlenk flask with Ru complex and phosphoramidite; mixt. heated at reflux in oil bath for 1 h; solvent removed under vac.; solid purified by flash chromy. on silica column with CH2Cl2/Et2O; removed under vac.; elem. anal.;
DOI:10.1002/ejic.201001176

Reference yield: 94.0%

: 1190481-97-0
[RuCl(indenyl)(PPh₃)P(OC₁₀H₆)2N(CH₂Ph)2]

: 17382-05-7
3-(2-Furyl)-3-hydroxy-1-butyn

: 17950-40-2
triethyloxonium hexaflourophosphate

: [Ru((2-furyl)methylallenylidene)(indenyl)(PPh₃)P(OC₁₀H₆)2N(CH₂Ph)2]PF₆

Guidance literature:: In dichloromethane; CH2Cl2 added to Schlenk flask contg. Ru complex; cooled to 0°C; (EtO)3PF6 in CH2Cl2 added; after 1 h, butynol deriv. added; after 30 min cold bath removed. soln. warmed to room temp. over 30 min; solvent removed under vac.; washed with Et2O, dried under vac.; elem. anal.;
DOI:10.1002/ejic.201001176

Reference yield: 85.0%

: 75-09-2
dichloromethane

: 1190481-97-0
[RuCl(indenyl)(PPh₃)P(OC₁₀H₆)2N(CH₂Ph)2]

: 17950-40-2
triethyloxonium hexaflourophosphate

: 3923-52-2
1,1-diphenyl-2-propyn-1-ol

: [Ru(diphenylallenylidene)(indenyl)(PPh₃)P(OC₁₀H₆)2N(CH₂Ph)2](PF₆)

Guidance literature:: In dichloromethane; CH2Cl2 added to Schlenk flask contg. Ru complex; cooled to 0°C; (EtO)3PF6 in CH2Cl2 added; after 1 h, propynol deriv. added; after 30 mincold bath removed. soln. warmed to room temp. over 30 min; solvent removed under vac.; washed with Et2O, dried under vac.; elem. anal.;
DOI:10.1002/ejic.201001176