1,1'-bis[p-(ethoxycarbonyl)phenyl]ferrocene

Base Information

Chemical Name:1,1'-bis[p-(ethoxycarbonyl)phenyl]ferrocene
CAS No.:87607-45-2
Molecular Formula:C₂₈H₂₆FeO₄
Molecular Weight:482.359
Hs Code.:

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Chemical Property of 1,1'-bis[p-(ethoxycarbonyl)phenyl]ferrocene

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Technology Process of 1,1'-bis[p-(ethoxycarbonyl)phenyl]ferrocene

There total 1 articles about 1,1'-bis[p-(ethoxycarbonyl)phenyl]ferrocene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 26.0%

: 102-54-5,55404-68-7
ferrocene

: 4-Ethoxycarbonyl-benzenediazonium; hydrogen sulfate

: 58482-66-9
(p-ethoxycarbonylphenyl)ferrocene

: 87607-45-2
1,1'-bis[p-(ethoxycarbonyl)phenyl]ferrocene

Guidance literature:: In water; acetic acid; soln. of diazotized salt in 10% sulfuric acid added rapidly to soln. offerrocene in acetic acid under N2, stirred overnight at room temp., poured into water; extd. with CHCl3, ext. washed with 5% aq. NaHCO3 and brine, dried over anhyd. MgSO4, filtered, concd., purified by column chromy. (SiO2, benzene); elem. anal.;
DOI:10.1246/bcsj.56.2023

Reference yield: 89.0%

: 16853-85-3
lithium aluminium tetrahydride

: 87607-45-2
1,1'-bis[p-(ethoxycarbonyl)phenyl]ferrocene

: 87607-47-4
1,1'-bis[p-(hydroxymethyl)phenyl]ferrocene

Guidance literature:: In diethyl ether; benzene; to suspn. of LiAlH4 in anhyd. Et2O added dropwise soln. of Fe complex in dry benzene at room temp. during 1 h, heated under reflux for addnl. 5h, decompd. with cold water; org. layer washed successively with 5% hydrochloric acid, 5% NaHCO3 soln., and brine, dried over anhyd. MgSO4, evapd., purified by column chromy. (SiO2, CHCl3), recrystd. from ethanol; elem. anal.;
DOI:10.1246/bcsj.56.2023