58482-66-9Relevant academic research and scientific papers
Some newly synthesized ferrocene based esters: Characterization, DNA interaction and DFT studies
Nisa, Zaib un,Gul, Asghari,Akhter, Zareen,Nadeem, Muhammad Arif,Tahir, M. Nawaz,Ahmed, Moiz Uddin
, p. 130 - 140 (2016/09/04)
A series of aromatic/aliphatic ferroceneyl-esters (E1–E10) was synthesized by condensation of 4-ferrocenyl benzoic acid (FB) with various alcohols (A1–A10). Structural elucidation of these esters was carried out by FT-IR,1HNMR and UV–visible sp
Ultrafast excited-state dynamics of ferrocene-bridge-acceptor system
Mohammed, Omar F.,Sarhan, Abdelwareth A.O.
, p. 17 - 21 (2010/09/17)
We employed both femtosecond fluorescence up-conversion and transient absorption techniques with ～150 fs time resolution to study the excited-state deactivation process of an intra-molecular charge transfer model compound, 4-(ferrocen-1-yl)benzylidene-malononitrile (Fc-ph-DCV), which consists of ferrocene (Fc) unit as an electron donor, dicyanovinly (DCV) as an electron acceptor and phenyl (ph) ring as the central bridge. The results showed that after photoexcitation into the higher excited S2 state, ultrafast internal conversion into S1 takes place. The rate of S2 → S1 internal conversion is markedly faster (with a typical time of 120 fs ± 20 fs) than the diffusive solvation process. On the other hand, the lifetime of the relaxed S1 state was strongly dependent on the solvent polarity, changing from 40 to 50 ps in acetonitrile to ～20 ps in cyclohexane. Time-resolved fluorescence data also showed subpicosecond transient component that is attributable to the spectral relaxation caused by solvation and/or vibrational relaxation in the S1 state.
Synthesis, characterization and in vitro anti-cancer activity of N-(ferrocenyl)benzoyl tri- and tetrapeptide esters
Corry, Alan J.,Mooney, áine,O'Sullivan, Dermot,Kenny, Peter T.M.
, p. 2957 - 2961 (2009/09/26)
N-ortho, N-meta and N-para-(ferrocenyl)benzoyl tri- and tetrapeptide esters (2-7) were prepared by coupling ortho, meta and para-ferrocenyl benzoic acids to the tri- and tetrapeptide ethyl esters of GlyGlyGly(OEt) and GlyGlyGlyGly(OEt) in the presence of
Bis(ferrocenyl)mercury as a source of ferrocenyl moiety in Pd-catalyzed reactions of carbon-carbon bond formation
Beletskaya, Irina P.,Tsvetkov, Alexei V.,Latyshev, Gennadij V.,Tafeenko, Victor A.,Lukashev, Nikolai V.
, p. 653 - 663 (2007/10/03)
The application of bis(ferrocenyl)mercury as a source of ferrocenyl group in Pd-catalyzed reactions with aryl halides, acid chlorides and electrophilic alkynes has been demonstrated. The formation of dimethyl-(Z)-2,3-di(ferrocenyl)-2-butenedioate in Pd-catalyzed addition of bis(ferrocenyl)mercury to dimethylacetylenedicarboxylate has been confirmed by X-ray analysis.
Synthesis of Orthocycloorthocyclo(1,1')ferrocenophane and Paracycloparacyclo(1,1')ferrocenophane
Shimizu, Iwao,Umezawa, Hiroshi,Kanno, Toshihiro,Izumi, Taeko,Kasahara, Akira
, p. 2023 - 2028 (2007/10/02)
syn- and anti-Orthocycloorthocyclo(1,1')ferrocenophan-7-enes were synthesized via an intramolecular reductive coupling of 1,1'-bis(o-formylphenyl)ferrocene with low valent titanium reagents. syn- and anti-Orthocycloorthocyclo(1,1')ferroc
