[Ir(OAc)2(C₅H₄NC₅H₂NPh)(4,4'-di-tert-butyl-2,2'-bipyridine)]

Base Information

• Chemical Name: [Ir(OAc)2(C₅H₄NC₅H₂NPh)(4,4'-di-tert-butyl-2,2'-bipyridine)]
• CAS No.: 1160657-88-4
• Molecular Formula: C₃₈H₄₁IrN₄O₄
• Molecular Weight: 809.988
• Mol file: 1160657-88-4.mol

Synonyms:

Chemical Property of [Ir(OAc)2(C₅H₄NC₅H₂NPh)(4,4'-di-tert-butyl-2,2'-bipyridine)]

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [Ir(OAc)2(C₅H₄NC₅H₂NPh)(4,4'-di-tert-butyl-2,2'-bipyridine)]

There total 2 articles about [Ir(OAc)2(C₅H₄NC₅H₂NPh)(4,4'-di-tert-butyl-2,2'-bipyridine)] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 48.9%

[Ir(OTf)(CH3)(C5H4NC5H2NPh)(4,4'-di-tert-butyl-2,2'-bipyridine)] (937206-05-8) + water (7732-18-5) + acetic acid (64-19-7,77671-22-8) → [Ir(OAc)2(C5H4NC5H2NPh)(4,4'-di-tert-butyl-2,2'-bipyridine)] (1160657-88-4) + [Ir(triflato)(C5H4NC5H2NPh)(4,4'-di-tert-butyldipyridyl)(acetato)]*H2O

Guidance literature:

In acetic acid; (Ar); using Schlenk techniques; dissolving of Ir(4,4'-di-tert-butyldipyridyl)(OTf)(Me)(C5H4NC5H2NC6H5) in CH3COOH; stirring for 2 h; diluting with H2O; extn. with CH2Cl2; washing with H2O; drying with MgSO4; removal of solvent under vac., sonication with ether, pptn. with pentane; redissolving; pptn. with pentane; monitoring by NMR; elem. anal.;

DOI:10.1021/om900014h

Reference yield:

pyridine (110-86-1) + [Ir(OTf)(CH3)(C5H4NC5H2NPh)(4,4'-di-tert-butyl-2,2'-bipyridine)] (937206-05-8) + acetic acid (64-19-7,77671-22-8) → [Ir(OAc)2(C5H4NC5H2NPh)(4,4'-di-tert-butyl-2,2'-bipyridine)] (1160657-88-4) + [Ir(triflato)(C5H4NC5H2NPh)(4,4'-di-tert-butyldipyridyl)(acetato)](triflate) (1207161-55-4)

Guidance literature:

In acetic acid; benzene; (Ar); using Schlenk techniques; heating of Ir(4,4'-di-tert-butyldipyridyl)(OTf)(Me)(C5H4NC5H2NC6H5) in 1:1 C6H6/CH3COOH soln. at 170°C for 15 h; removal of volatiles; treatment with py; NMR analysis;

DOI:10.1021/om900014h

upstream raw materials:

[Ir(OTf)(CH₃)(C₅H₄NC₅H₂NPh)(4,4'-di-tert-butyl-2,2'-bipyridine)]

water

acetic acid

pyridine