Mn₂(CO)9CS

Base Information

• Chemical Name: Mn₂(CO)9CS
• CAS No.: 125638-56-4
• Molecular Formula: C₁₀Mn₂O₉S
• Molecular Weight: 406.047
• Mol file: 125638-56-4.mol

Synonyms:

Chemical Property of Mn₂(CO)9CS

Chemical Property:

Purity/Quality:

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Technology Process of Mn₂(CO)9CS

There total 1 articles about Mn₂(CO)9CS which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

thiophosgene (463-71-8) + potassium[manganese(pentacarbonyl)] (15693-51-3) → dimanganese decacarbonyl (10170-69-1) + pentacarbonylchloromanganese(I) (14100-30-2) + Mn2(CO)9CS (125568-31-2,125638-56-4)

Guidance literature:

In pentane; (N2); addn. of excess SCCl2 to Mn-complex in pentane, stirring (10 min, 0°C), stirring (30 min, room temp.); filtration, evapn. to dryness, sublimation (high vac., 30-40°C), chromy. (Al2O3, pentane); product mixt. not sepd.; total yield 12-14%;

DOI:10.1021/om00117a050

upstream raw materials:

thiophosgene

potassium[manganese(pentacarbonyl)]