pentacarbonylchloromanganese

Base Information

• Chemical Name: pentacarbonylchloromanganese
• CAS No.: 14100-30-2
• Molecular Formula: C5Cl Mn O5
• Molecular Weight: 230.443
• Mol file: 14100-30-2.mol

Synonyms:Manganese,chloropentacarbonyl- (7CI); Manganese, pentacarbonylchloro- (8CI);Chloropentacarbonylmanganese; Manganese carbonyl chloride (Mn(CO)5Cl);Manganese pentacarbonyl chloride; Pentacarbonylchloromanganese;Pentacarbonylmanganese chloride

Chemical Property of pentacarbonylchloromanganese

Chemical Property:

• PSA: 0.00000
• LogP: -4.03600

Purity/Quality:

98%Min ^*data from raw suppliers

MANGANESE PENTACARBONYL CHLORIDE 95.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of pentacarbonylchloromanganese

There total 86 articles about pentacarbonylchloromanganese which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

dimanganese decacarbonyl (10170-69-1) → pentacarbonylchloromanganese(I) (14100-30-2) + hexachloroethane (67-72-1)

Guidance literature:

With tetrachloromethane; In tetrachloromethane; byproducts: CCl3; Irradiation (UV/VIS); Irradiation λ >350 nm, CCl4, Ar atm.;; detected by IR spectra and GCA;;

Reference yield: 99.0%

bis(triphenylphosphineiminium) pentacarbonylmanganate(1-) (52542-59-3,192520-17-5) + chloroacetic acid ethyl ester (105-39-5) → dimanganese decacarbonyl (10170-69-1) + pentacarbonylchloromanganese(I) (14100-30-2) + η1-(CH2COOEt) manganese pentacarbonyl

Guidance literature:

In tetrahydrofuran; (N2 or Ar); 25°C, rapid mixing; determination by NMR;

Reference yield: 98.0%

bis(triphenylphosphineiminium) pentacarbonylmanganate(1-) (52542-59-3,192520-17-5) + (E)-methyl 4-chlorobut-2-enoate (999-54-2) → dimanganese decacarbonyl (10170-69-1) + pentacarbonylchloromanganese(I) (14100-30-2) + η1-4-oxo-4-ethoxy-2-butenyl manganese pentacarbonyl

Guidance literature:

In tetrahydrofuran; (N2 or Ar), 25°C, stirring for 30 min in a round-bottom flask; solvent is removed under reduced pressure, extd. with pentane, chromy. on silica gel(CH2Cl2), determined by (55)Mn-NMR;

upstream raw materials:

tetrachloromethane

dimanganese decacarbonyl

2-methyltetrahydrofuran

acetonitrile

Downstream raw materials:

{(palladium)(manganese)(Cl)(carbonyl)3(μ-dppm)2}

fac-{manganese(Cl)(carbonyl)3(dppm)}

Mn(CO)4(P(C₆H₅)3)Cl

Mn(CO)3(P(C₆H₅)3)2Cl

Refernces

• 1、 Dobbie, R. C.. "". . . Retrieved 1971.
• 2、 He, Yu-Tao,Karimata, Ayumu,Gladkovskaya, Olga,Khaskin, Eugene,Fayzullin, Robert R.,Sarbajna, Abir,Khusnutdinova, Julia R.. "C-C Bond Elimination from High-Valent Mn Aryl Complexes". . p. 2320 - 2331. Retrieved 2021.
• 3、 Hernandez, Jose G.,Butler, Ian S.,Friscic, Tomislav. "Multi-step and multi-component organometallic synthesis in one pot using orthogonal mechanochemical reactions". . p. 3576 - 3582. Retrieved 2014/08/18.