17²,17⁴-diphenyl-17³H-5,10,15,20-tetraazatribenzo[b,g,l][1,4]diazepino[2,3-q]porphyrin

Base Information

• Chemical Name: 17²,17⁴-diphenyl-17³H-5,10,15,20-tetraazatribenzo[b,g,l][1,4]diazepino[2,3-q]porphyrin
• CAS No.: 1121800-92-7
• Molecular Formula: C₄₃H₂₆N₁₀
• Molecular Weight: 682.746
• Mol file: 1121800-92-7.mol

Synonyms:

Chemical Property of 17²,17⁴-diphenyl-17³H-5,10,15,20-tetraazatribenzo[b,g,l][1,4]diazepino[2,3-q]porphyrin

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 17²,17⁴-diphenyl-17³H-5,10,15,20-tetraazatribenzo[b,g,l][1,4]diazepino[2,3-q]porphyrin

There total 6 articles about 17²,17⁴-diphenyl-17³H-5,10,15,20-tetraazatribenzo[b,g,l][1,4]diazepino[2,3-q]porphyrin which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 60.0%

magnesium(II) 5,7-diphenyl-1,4-diazepinotribenzoporphyrazinate (1256964-84-7) → 5,7-diphenyl-1,4-diazepinotribenzoporphyrazine (1121800-92-7)

Guidance literature:

With trifluoroacetic acid; Darkness;

DOI:10.1134/S1070428012110115

Reference yield: 20.0%

phthalonitrile (91-15-6) + 5,7-diphenyl-6H-1,4-diazepine-2,3-dicarbonitrile (56984-07-7) → 29H,31H-phthalocyanine (574-93-6) + 172,174-diphenyl-173H-5,10,15,20-tetraazatribenzo[b,g,l][1,4]diazepino[2,3-q]porphyrin (1121800-92-7) + 172-phenyl-5,10,15,20-tetraazatribenzo[b,g,l]pyrazino[2,3-q]porphyrin-173(174H)-one (1539304-52-3)

Guidance literature:

With lithium butoxide; In butan-1-ol; for 4h; Reflux;

DOI:10.1134/S1070428013120178

Reference yield:

1,3-diphenylpropanedione (120-46-7,61346-73-4) → 5,7-diphenyl-1,4-diazepinotribenzoporphyrazine (1121800-92-7)

Guidance literature:

Multi-step reaction with 3 steps

1: phosphorus pentoxide / ethanol / 3 h / 20 °C / Reflux

2: butan-1-ol; magnesium / 4 h / 118 °C

3: trifluoroacetic acid / Darkness

With phosphorus pentoxide; magnesium; trifluoroacetic acid; butan-1-ol; In ethanol;

DOI:10.1134/S1070428012110115

upstream raw materials:

phthalonitrile

5,7-diphenyl-6H-1,4-diazepine-2,3-dicarbonitrile

magnesium(II) 5,7-diphenyl-1,4-diazepinotribenzoporphyrazinate

1,3-diphenylpropanedione

Downstream raw materials:

(2,3-diphenyl)pyrazinotribenzoporphyrazine

(2-phenyl)imidazolotribenzoporphyrazine