CID 10900373

Base Information

• Chemical Name: CID 10900373
• CAS No.: 16369-40-7
• Molecular Formula: C2Cl2 O2 Ru
• Molecular Weight: 227.997
• Mol file: 16369-40-7.mol

Synonyms:

Chemical Property of CID 10900373

Chemical Property:

• PSA: 0.00000
• LogP: 1.14480
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 0
• Exact Mass: 227.831875
• Heavy Atom Count: 7
• Complexity: 12.8

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: [C-]#[O+].[C-]#[O+].Cl[Ru]Cl

Technology Process of CID 10900373

There total 6 articles about CID 10900373 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

ruthenium(III)chloride (10049-08-8,63767-78-2) → dicarbonyldichlororuthenium(II) (16369-40-7)

Guidance literature:

With CO; In 2-methoxy-ethanol; RuCl3 dissolved in 2-methoxyethanol, soln. heated at reflux as stream of CO passed into it for 170-210 min; solvent removed at reduced pressure;

Reference yield: 100.0%

ruthenium trichloride hydrate (14898-67-0) → dicarbonyldichlororuthenium(II) (16369-40-7)

Guidance literature:

With hydrogenchloride; formic acid; In hydrogenchloride; formic acid; RuCl3*99H2O in 90% HCO2H and concd. HCl refluxed for 18 h, addn. of HCO2H and HCl, refluxed for 4 h; evapn. to dryness, extn. (methanol), evapn. to dryness;

DOI:10.1016/0022-328X(89)87095-0

Reference yield: 96.0%

ruthenium trichloride (63767-78-2) + formaldehyd (50-00-0,30525-89-4,61233-19-0) → dicarbonyldichlororuthenium(II) (16369-40-7)

Guidance literature:

With formic acid; at 110 ℃; for 18h; Inert atmosphere;

DOI:10.1021/acs.inorgchem.1c00615

upstream raw materials:

ruthenium trichloride hydrate

ruthenium(III)chloride

ruthenium trichloride

formaldehyd

Downstream raw materials:

cis-dicarbonyldichlorobis(triphenylphosphine)ruthenium(II)

trans-dicarbonyldichlorobis((S,S)-o-phenylenebis(methylphenylphosphine))ruthenium(II)

trans-dicarbonyldichloro((RS)-o-phenylenebis(methylphenylphosphine))ruthenium(II)

(-)589-trans-dicarbonyldichloro((S,S)-o-phenylenebis(methylphenylphosphine))ruthenium(II)

Refernces

• 1、 Roberto, Dominique,Psaro, Rinaldo,Ugo, Renato. "Surface-mediated organometallic synthesis: High-yield preparations of {Ir(CO)3Cl}n, [Rh(CO)2Cl]2, [Ru(CO)3Cl2]2, [Os(CO)3Cl2]2, [Ir4(CO)12], and [Rh6(CO)16] by reductive carbonylation, under mild conditions, of silica-supported metal chlorides". . p. 2292 - 2296. Retrieved 2008/10/08.
• 2、 Grocott, Stephen C.,Wild, Stanley Bruce. "Metal complexes containing diastereoisomers and enantiomers of o-phenylenebis(methylphenylarsine) and its Phosphorus analogue. 4. Preparation and properties of carbonyl halide derivatives of ruthenium(II)". . p. 3535 - 3540. Retrieved 2008/10/08.