bis[methyl(phenylethynyl)chloromethyloxy]praseodymium chloride monotetrahydrofuranate

Base Information

• Chemical Name: bis[methyl(phenylethynyl)chloromethyloxy]praseodymium chloride monotetrahydrofuranate
• CAS No.: 1259079-26-9
• Molecular Formula: C₄H₈O*C₂₀H₁₆Cl₃O₂Pr
• Molecular Weight: 607.719
• Mol file: 1259079-26-9.mol

Synonyms:

Chemical Property of bis[methyl(phenylethynyl)chloromethyloxy]praseodymium chloride monotetrahydrofuranate

Chemical Property:

Purity/Quality:

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Useful:

Technology Process of bis[methyl(phenylethynyl)chloromethyloxy]praseodymium chloride monotetrahydrofuranate

There total 1 articles about bis[methyl(phenylethynyl)chloromethyloxy]praseodymium chloride monotetrahydrofuranate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

hexa(tetrahydrofuranate)dipraseodymium tris(triphenylethynylcuprate) + acetyl chloride (75-36-5) → copper(I) phenylacetylide (13146-23-1) + bis[methyl(phenylethynyl)chloromethyloxy]praseodymium chloride monotetrahydrofuranate (1259079-26-9)

Guidance literature:

In tetrahydrofuran; byproducts: C6H5CCC(Cl)(CH3)OCOCH3; Schlenk techniques; addn. of AcCl to soln. of Cu complex (1:8) in THF, storage at room temp. for 5 d; isolation of solid, washing with THF, evapn., addn. of hexane, isolationof solid, drying, elem. anal.;

DOI:10.1134/S1070363210090082

upstream raw materials:

acetyl chloride