[Ru(triphenylphosphine)2Cl(η5-t-butoxycarbonylcyclopentadienyl)]

Base Information

Chemical Name:[Ru(triphenylphosphine)2Cl(η5-t-butoxycarbonylcyclopentadienyl)]
CAS No.:1025008-77-8
Molecular Formula:C₄₆H₄₃ClO₂P₂Ru
Molecular Weight:826.317
Hs Code.:

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Chemical Property of [Ru(triphenylphosphine)2Cl(η5-t-butoxycarbonylcyclopentadienyl)]

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Technology Process of [Ru(triphenylphosphine)2Cl(η5-t-butoxycarbonylcyclopentadienyl)]

There total 1 articles about [Ru(triphenylphosphine)2Cl(η5-t-butoxycarbonylcyclopentadienyl)] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

: 15529-49-4,41756-81-4
tris(triphenylphosphine)ruthenium(II) chloride

: t-butoxycarbonylcyclopentadienyllithium

: 1025008-77-8
[Ru(triphenylphosphine)2Cl(η5-t-butoxycarbonylcyclopentadienyl)]

Guidance literature:: In tetrahydrofuran; byproducts: LiCl; (N2/Ar); using Schlenk techniques; stirring of soln. of RuCl2(PPh3)3 andLiC5H4COO(t-Bu) in THF at room temp. for 2 h; addn. of hexanes; pptn., filtration, washing several times with hexanes;drying under vac., passing through silica with Et2O; evapn. of solvent; elem. anal.;
DOI:10.1016/j.jorganchem.2008.01.030

Reference yield: 80.0%

: 16029-98-4
trimethylsilyl iodide

: 1025008-77-8
[Ru(triphenylphosphine)2Cl(η5-t-butoxycarbonylcyclopentadienyl)]

: 64896-28-2
(2S,3S)-2,3-bis(diphenylphosphino)butane

: [Ru((2S,3S)-bis(diphenylphopshino)butane)I(η5-C5H4COOH)]

Guidance literature:: In toluene; (N2/Ar); using Schlenk techniques; reflux of soln. of RuCl(PPh3)2(C5H4COOCMe3) and (PPh2CHMe)2 in MePh for 16 h; loading on column (silica); elution with C6H6 and C6H6/ether; evapn., treatment with SiMe3I/CH2Cl2 for 0.5 h; addn. of H2O; stirring for 20h; removal of volatile components by vac., filtration, washing with MeOH and Et2O; drying under vac., elem. anal.;
DOI:10.1016/j.jorganchem.2008.01.030

Reference yield: 68.0%

: 1025008-77-8
[Ru(triphenylphosphine)2Cl(η5-t-butoxycarbonylcyclopentadienyl)]

: 1663-45-2
1,2-bis-(diphenylphosphino)ethane

: 1025008-78-9
[Ru(1,2-bis(diphenylphosphino)ethane)Cl(η5-t-butoxycarbonylcyclopentadienyl)]

Guidance literature:: In toluene; (N2/Ar); using Schlenk techniques; reflux of suspn. of RuCl(PPh3)2(C5H4COO(t-Bu)) with dppe in toluene for 18 h; cooling to room temp., chromy. (silica); elution with benzene and then with benzene/ether (1/5); evapn. of solvent; elem. anal.;
DOI:10.1016/j.jorganchem.2008.01.030