[Ru(1,2-bis(diphenylphosphino)ethane)Cl(η5-t-butoxycarbonylcyclopentadienyl)]

Base Information

Chemical Name:[Ru(1,2-bis(diphenylphosphino)ethane)Cl(η5-t-butoxycarbonylcyclopentadienyl)]
CAS No.:1025008-78-9
Molecular Formula:C₃₆H₃₇ClO₂P₂Ru
Molecular Weight:700.159
Hs Code.:

Synonyms:

Suppliers and Price of [Ru(1,2-bis(diphenylphosphino)ethane)Cl(η5-t-butoxycarbonylcyclopentadienyl)]

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of [Ru(1,2-bis(diphenylphosphino)ethane)Cl(η5-t-butoxycarbonylcyclopentadienyl)]

Chemical Property:

Purity/Quality:: 98% ^*data from raw suppliers

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Technology Process of [Ru(1,2-bis(diphenylphosphino)ethane)Cl(η5-t-butoxycarbonylcyclopentadienyl)]

There total 1 articles about [Ru(1,2-bis(diphenylphosphino)ethane)Cl(η5-t-butoxycarbonylcyclopentadienyl)] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 68.0%

: 1025008-77-8
[Ru(triphenylphosphine)2Cl(η5-t-butoxycarbonylcyclopentadienyl)]

: 1663-45-2
1,2-bis-(diphenylphosphino)ethane

: 1025008-78-9
[Ru(1,2-bis(diphenylphosphino)ethane)Cl(η5-t-butoxycarbonylcyclopentadienyl)]

Guidance literature:: In toluene; (N2/Ar); using Schlenk techniques; reflux of suspn. of RuCl(PPh3)2(C5H4COO(t-Bu)) with dppe in toluene for 18 h; cooling to room temp., chromy. (silica); elution with benzene and then with benzene/ether (1/5); evapn. of solvent; elem. anal.;
DOI:10.1016/j.jorganchem.2008.01.030

Reference yield: 88.0%

: 16029-98-4
trimethylsilyl iodide

: 1025008-78-9
[Ru(1,2-bis(diphenylphosphino)ethane)Cl(η5-t-butoxycarbonylcyclopentadienyl)]

: 7732-18-5
water

: 1025008-79-0
[Ru(1,2-bis(diphenylphosphino)ethane)I(η5-C5H4COOH)]

Guidance literature:: In dichloromethane; (N2/Ar); using Schlenk techniques; stirring of soln. of RuCl(dppe)(C5H4COO(t-Bu)) with Me3SiI for 30 min; addn. of H2O; stirring overnight; removal of volatile components by vac.; filtration, evapn.; washing withMeOH, Et2O and CH2Cl2; drying under vac., elem. anal.;
DOI:10.1016/j.jorganchem.2008.01.030

Reference yield: 58.0%

: 67-56-1
methanol

: 1025008-78-9
[Ru(1,2-bis(diphenylphosphino)ethane)Cl(η5-t-butoxycarbonylcyclopentadienyl)]

: 1025008-83-6
[Ru(1,2-bis(diphenylphosphino)ethane)H(η5-t-butoxycarbonylcyclopentadienyl)]

Guidance literature:: With sodium; In methanol; (N2/Ar); using Schlenk techniques; treatment of soln. of RuCl(dppe)(C5H4COO(t-Bu)) in MeOH with sodium; reflux for 18 h; evapn. of solvent; extn. with benzene; filtration, evapn.; washing with MeOH several times; drying under vac., elem. anal.;
DOI:10.1016/j.jorganchem.2008.01.030