[6,6'-bis(2,2-diphenyl-2-sulfanylethyl)-2,2'-bipyridinato]chloroiron(III)

Base Information

Chemical Name:[6,6'-bis(2,2-diphenyl-2-sulfanylethyl)-2,2'-bipyridinato]chloroiron(III)
CAS No.:203871-19-6
Molecular Formula:C₃₈H₃₀ClFeN₂S₂
Molecular Weight:670.102
Hs Code.:

Synonyms:

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Chemical Property of [6,6'-bis(2,2-diphenyl-2-sulfanylethyl)-2,2'-bipyridinato]chloroiron(III)

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Technology Process of [6,6'-bis(2,2-diphenyl-2-sulfanylethyl)-2,2'-bipyridinato]chloroiron(III)

There total 2 articles about [6,6'-bis(2,2-diphenyl-2-sulfanylethyl)-2,2'-bipyridinato]chloroiron(III) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 60.0%

: 7705-08-0
iron(III) chloride

: 203871-22-1
2,2’-(2,2’-bipyridine-6,6’-diyl)bis(1,1’-diphenylethanethiolate)

: 203871-19-6
[6,6'-bis(2,2-diphenyl-2-sulfanylethyl)-2,2'-bipyridinato]chloroiron(III)

Guidance literature:: With NaH; In N,N-dimethyl-formamide; byproducts: NaCl; (argon); addn. of the ligand to NaH in DMF (room temp., 15 min), addn. of FeCl3 in DMF, stirring (room temp., 1 h), then exposure to air; concn., pptn. upon addn. to Et2O, filtration, washing (Et2O), dissoln. (CH2Cl2), filtration, slow evapn.; elem. anal.;
DOI:10.1039/a706664c

Reference yield:

: iron(III) chloride

: 203871-22-1
2,2’-(2,2’-bipyridine-6,6’-diyl)bis(1,1’-diphenylethanethiolate)

: 203871-19-6
[6,6'-bis(2,2-diphenyl-2-sulfanylethyl)-2,2'-bipyridinato]chloroiron(III)

Guidance literature:: 2,2’-(2,2’-bipyridine-6,6’-diyl)bis(1,1’-diphenylethanethiolate); With sodium hydride; In tetrahydrofuran; mineral oil; at 19.84 ℃; for 0.333333h;

iron(III) chloride; In tetrahydrofuran; mineral oil; for 1h;
DOI:10.1002/chem.201705989

Reference yield: 70.0%

: tetra-n-butylammonium hydroxide

: 203871-19-6
[6,6'-bis(2,2-diphenyl-2-sulfanylethyl)-2,2'-bipyridinato]chloroiron(III)

: μ-oxo-bis[6,6'-bis(2,2-diphenyl-2-sulfanylethyl)-2,2'-bipyridinato]iron(III) dihydrate

Guidance literature:: In methanol; dichloromethane; addn. of Bu4NOH in MeOH to the Fe complex in CH2Cl2; filtration, washing (H2O); elem. anal.;
DOI:10.1039/a706664c