2,2’-(2,2’-bipyridine-6,6’-diyl)bis(1,1’-diphenylethanethiolate)

Base Information

• Chemical Name: 2,2’-(2,2’-bipyridine-6,6’-diyl)bis(1,1’-diphenylethanethiolate)
• CAS No.: 203871-22-1
• Molecular Formula: C₃₈H₃₂N₂S₂
• Molecular Weight: 580.817
• Mol file: 203871-22-1.mol

Synonyms:2,2’-(2,2’-bipyridine-6,6’-diyl)bis(1,1’-diphenylethanethiolate)

Chemical Property of 2,2’-(2,2’-bipyridine-6,6’-diyl)bis(1,1’-diphenylethanethiolate)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 2,2’-(2,2’-bipyridine-6,6’-diyl)bis(1,1’-diphenylethanethiolate)

There total 1 articles about 2,2’-(2,2’-bipyridine-6,6’-diyl)bis(1,1’-diphenylethanethiolate) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

6,6'-Bis-[2,2-diphenyl-2-(tetrahydro-pyran-2-ylsulfanyl)-ethyl]-[2,2']bipyridinyl → 2,2’-(2,2’-bipyridine-6,6’-diyl)bis(1,1’-diphenylethanethiolate) (203871-22-1)

Guidance literature:

With silver nitrate; In pyridine; methanol; ethyl acetate; for 5h; Ambient temperature;

DOI:10.1039/a706664c

Reference yield: 80.0%

iron(II) tetrafluoroborate hexahydrate + sodium hydride (7646-69-7) + 2,2’-(2,2’-bipyridine-6,6’-diyl)bis(1,1’-diphenylethanethiolate) (203871-22-1) → C76H61Fe2N4S4(1+)*BF4(1-)

Guidance literature:

sodium hydride; 2,2’-(2,2’-bipyridine-6,6’-diyl)bis(1,1’-diphenylethanethiolate); In tetrahydrofuran; at 19.84 ℃; for 0.333333h; Glovebox; Inert atmosphere;

iron(II) tetrafluoroborate hexahydrate; In tetrahydrofuran; for 1h; Glovebox; Inert atmosphere;

DOI:10.1021/jacs.9b02011

Reference yield: 79.0%

zinc diacetate (557-34-6) + 2,2’-(2,2’-bipyridine-6,6’-diyl)bis(1,1’-diphenylethanethiolate) (203871-22-1) → [Zn(2,2'-(2,2'-bipyridine-6,6'-diyl)bis(1,1-diphenylethanethiolate(-2H))] (1335107-86-2)

Guidance literature:

With NaH; In tetrahydrofuran; methanol; (Ar); Schlenk technique; NaH was added to soln. of ligand in THF; after 20 min filtered; soln. of zn salt in MeOH/THF (1/4) was added; reacted for 1 h; evapd. (vac.); extd. (CH2Cl2); evapd. (vac.); washed (MeOH); recrystd. (CH2Cl2/MeOH, 2/1); elem. anal.;

DOI:10.1021/ic200899w

Downstream raw materials:

[6,6'-bis(2,2-diphenyl-2-sulfanylethyl)-2,2'-bipyridinato]chloroiron(III)

[Zn(2,2'-(2,2'-bipyridine-6,6'-diyl)bis(1,1-diphenylethanethiolate(-2H))]