cis-(BzlPh₂P)2PtCl₂

Base Information

• Chemical Name: cis-(BzlPh₂P)2PtCl₂
• CAS No.: 61586-06-9
• Molecular Formula: C₃₈H₃₄Cl₂P₂Pt
• Molecular Weight: 818.621
• Mol file: 61586-06-9.mol

Synonyms:

Chemical Property of cis-(BzlPh₂P)2PtCl₂

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

Useful:

Technology Process of cis-(BzlPh₂P)2PtCl₂

There total 4 articles about cis-(BzlPh₂P)2PtCl₂ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 74.1%

Pt{C6H4CH2P(C6H5)2}2 → cis-(BzlPh2P)2PtCl2 (61586-06-9)

Guidance literature:

With hydrogenchloride; In diethyl ether; chloroform; (Ar); to CHCl3 soln. of complex was added HCl in ether at 0°C and mixt. was stirred for 0.5 h at room temp.; soln. was concd. and pptd. with ether; recrystn. from CH2Cl2/pentane; elem. anal.;

DOI:10.1016/S0022-328X(00)85903-3

Reference yield:

(C6H4CH2P(C6H5)2)Pt(C6H4CH2N(CH3)2) (100333-09-3) → cis-(BzlPh2P)2PtCl2 (61586-06-9) + [(C6H5CH2)NH(CH3)2](1+)*[(C6H5CH2P(C6H5)2)PtCl3](1-)=[(C6H5CH2)NH(CH3)2][(C6H5CH2P(C6H5)2)PtCl3] (100365-87-5)

Guidance literature:

With hydrogenchloride; In diethyl ether; chloroform; soln. of Pt complex in CHCl3 treated with etheral soln. of HCl (excess)under Ar at room tepm., stirred for 0.5 h; yield of (PhCH2PPh2)2PtCl2 was increased when react. heated for 2-3 h; filtered (PhCH2PPh2)2PtCl2, allowed to stand for several d, filtered ((PhCH2PPh2)PtCl3)(PhCH2NHMe2) ; elem. anal.;

DOI:10.1016/0022-328X(85)88040-2

Reference yield:

dichloro(1,5-cyclooctadiene)platinum(ll) (12080-32-9) + benzyldiphenylphosphane (7650-91-1) → cis-(BzlPh2P)2PtCl2 (61586-06-9)

Guidance literature:

In chloroform-d1; stepwise addn. of phosphine (25°C); not isolated, reaction followed by (31)P- and (195)Pt-NMR spectroscopy;

DOI:10.1016/S0020-1693(00)84701-5

upstream raw materials:

dichloro(1,5-cyclooctadiene)platinum(ll)

benzyldiphenylphosphane

(C₆H₄CH₂P(C₆H₅)2)Pt(C₆H₄CH₂N(CH₃)2)