{3-(p-toluenesulphonyl)propyl}triphenyltin

Base Information

• Chemical Name: {3-(p-toluenesulphonyl)propyl}triphenyltin
• CAS No.: 77329-34-1
• Molecular Formula: C₂₈H₂₈O₂SSn
• Molecular Weight: 547.305
• Mol file: 77329-34-1.mol

Synonyms:

Chemical Property of {3-(p-toluenesulphonyl)propyl}triphenyltin

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of {3-(p-toluenesulphonyl)propyl}triphenyltin

There total 1 articles about {3-(p-toluenesulphonyl)propyl}triphenyltin which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 78.0%

{3-(p-tolylthio)propyl}triphenyltin (77329-29-4) + 3-chloro-benzenecarboperoxoic acid (937-14-4) → {3-(p-toluenesulphonyl)propyl}triphenyltin (77329-34-1)

Guidance literature:

In dichloromethane; addition of m-chloroperbenzoic acid (> 2 eq.) in CH2Cl2 to tin compound in CH2Cl2 at 0°C dropwise with stirring, stirring overnight; washing twice with 5% NaHCO3 soln., drying of organic layer with MgSO4, filtration, evapn., recrystn. (methanol), elem. anal.;

DOI:10.1016/S0022-328X(00)98614-5

Reference yield: 67.0%

{3-(p-toluenesulphonyl)propyl}triphenyltin (77329-34-1) + mercury dichloride → {3-(p-toluenesulphonyl)propyl}diphenyltin chloride (86012-06-8)

Guidance literature:

In ethanol; byproducts: C6H5HgCl; stirring of ethanol solution of starting compounds at 50°C for 3 h; cooling, filtration, evapn., crystn. (CHCl3/petroleum ether), elem. anal.;

DOI:10.1016/S0022-328X(00)98614-5

Reference yield:

{3-(p-toluenesulphonyl)propyl}triphenyltin (77329-34-1) → (C6H5)2BrSnCH2CH2CH2SO2C6H4CH3

Guidance literature:

With Br₂; In tetrachloromethane; byproducts: C6H5Br; dropwise addition of dilute bromine solution in CCl4 to CCl4 solution of tin compound at 0°C;

DOI:10.1016/S0022-328X(00)98614-5

upstream raw materials:

{3-(p-tolylthio)propyl}triphenyltin

3-chloro-benzenecarboperoxoic acid

Downstream raw materials:

(C₆H₅)2ISnCH₂CH₂CH₂SO₂C₆H₄CH₃

{3-(p-toluenesulphonyl)propyl}diphenyltin chloride