1-[tert-Butyl(dimethyl)silyl]-2-phenylethan-1-one

Base Information

Chemical Name:1-[tert-Butyl(dimethyl)silyl]-2-phenylethan-1-one
CAS No.:132150-43-7
Molecular Formula:C14H22OSi
Molecular Weight:234.414
Hs Code.:
DSSTox Substance ID:DTXSID60566334
Nikkaji Number:J1.762.338I
Wikidata:Q82451914

Synonyms:132150-43-7;1-[tert-Butyl(dimethyl)silyl]-2-phenylethan-1-one;DTXSID60566334

Suppliers and Price of 1-[tert-Butyl(dimethyl)silyl]-2-phenylethan-1-one

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 4 raw suppliers

Chemical Property of 1-[tert-Butyl(dimethyl)silyl]-2-phenylethan-1-one

Chemical Property:

Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:1
Rotatable Bond Count:4
Exact Mass:234.143991855
Heavy Atom Count:16
Complexity:244

Purity/Quality:: 99%, ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CC(C)(C)[Si](C)(C)C(=O)CC1=CC=CC=C1

Technology Process of 1-[tert-Butyl(dimethyl)silyl]-2-phenylethan-1-one

There total 7 articles about 1-[tert-Butyl(dimethyl)silyl]-2-phenylethan-1-one which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 64.0%

: 174135-28-5
2-benzyl-2-<(tert-butyl)dimethylsilyl>-1,3-dithiane

: 132150-43-7
(tert-butyl)dimethyl(phenylacetyl)silane

Guidance literature:: With mercury dichloride; cadmium(II) chloride; In water; acetone; toluene; for 1h; Heating;
DOI:10.1002/(SICI)1522-2675(19990407)82:4<561::AID-HLCA561>3.0.CO;2-U

Reference yield:

: tert-butyl-(1-methoxy-2-phenyl-vinyl)-dimethyl-silane

: 132150-43-7
(tert-butyl)dimethyl(phenylacetyl)silane

Guidance literature:: With hydrogenchloride; In tetrahydrofuran;
DOI:10.1016/j.tet.2004.10.082

Reference yield:

: 100-52-7
benzaldehyde

: 132150-43-7
(tert-butyl)dimethyl(phenylacetyl)silane

Guidance literature:: Multi-step reaction with 2 steps

1.1: n-BuLi / tetrahydrofuran

1.2: tetrahydrofuran

2.1: HCl / tetrahydrofuran

With hydrogenchloride; n-butyllithium; In tetrahydrofuran; 1.2: Peterson olefination;
DOI:10.1016/j.tet.2004.10.082