Rh₂Cl₂(CH₃CO₂)2(P(C₆H₅)2(C₆H₄Cl))2

Base Information

Chemical Name:Rh₂Cl₂(CH₃CO₂)2(P(C₆H₅)2(C₆H₄Cl))2
CAS No.:254100-76-0
Molecular Formula:C₄₀H₃₄Cl₄O₄P₂Rh₂
Molecular Weight:988.278
Hs Code.:

Rh<sub>2</sub>Cl<sub>2</sub>(CH<sub>3</sub>CO<sub>2</sub>)2(P(C<sub>6</sub>H<sub>5</sub>)2(C<sub>6</sub>H<sub>4</sub>Cl))2

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Chemical Property of Rh₂Cl₂(CH₃CO₂)2(P(C₆H₅)2(C₆H₄Cl))2

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Technology Process of Rh₂Cl₂(CH₃CO₂)2(P(C₆H₅)2(C₆H₄Cl))2

There total 2 articles about Rh₂Cl₂(CH₃CO₂)2(P(C₆H₅)2(C₆H₄Cl))2 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 75.0%

: 75-77-4
chloro-trimethyl-silane

: tetra[μ-acetato-bis(methanol)]dirhodium

: 35035-62-2
diphenyl (2‐chlorophenyl) phosphine

: 254100-76-0
Rh₂Cl₂(CH₃CO₂)2(P(C₆H₅)2(C₆H₄Cl))2

Guidance literature:: In neat (no solvent); stirring the Rh complex and Me3SiCl at 50°C for 1 h, addn. of thephosphine, stirring (room temp., 12 h); solvent removal (vac.), dissoln. (CH2Cl2/hexane), chromy. (SiO2/hexane; elution with CH2Cl2, then CH2Cl2/acetone);
DOI:10.1039/a903811f

Reference yield: 10.0%

: tetra[μ-acetato-bis(methanol)]dirhodium

: 35035-62-2
diphenyl (2‐chlorophenyl) phosphine

: 254100-76-0
Rh₂Cl₂(CH₃CO₂)2(P(C₆H₅)2(C₆H₄Cl))2

Guidance literature:: In chloroform; acetic acid; toluene; (argon); refluxing the Rh complex in toluene/acetic acid to complete dissoln., then addn. of the phosphine in CHCl3/toluene, reflux (30 min); solvent removal (vac.), dissoln. (CH2Cl2/hexane), chromy. (SiO2/hexane; elution with CH2Cl2/hexane, then CH2Cl2/hexane/acetone), evapn. (reducedpressure), crystn. (CH2Cl2/hexane);
DOI:10.1039/a903811f